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  • Two diastereoisomeric 4,8-anhydro-non-1-enitols were stereoselectively prepared and their terminal C=C bonds were transformed to corresponding aldehydes by ozonolysis. Each of them provided two cycloadducts via the Wittig reaction followed by Eu(fod)3 catalyzed cycloaddition to ethyl vinyl ether. The obtained cycloadducts were isolated and they are precursors for preparation of (1#3)-C-disaccharides.
  • Two diastereoisomeric 4,8-anhydro-non-1-enitols were stereoselectively prepared and their terminal C=C bonds were transformed to corresponding aldehydes by ozonolysis. Each of them provided two cycloadducts via the Wittig reaction followed by Eu(fod)3 catalyzed cycloaddition to ethyl vinyl ether. The obtained cycloadducts were isolated and they are precursors for preparation of (1#3)-C-disaccharides. (en)
Title
  • Study Towards the Stereoselective Synthesis of ?- and ß-C-(1#3)-linked Disaccharides
  • Study Towards the Stereoselective Synthesis of ?- and ß-C-(1#3)-linked Disaccharides (en)
skos:prefLabel
  • Study Towards the Stereoselective Synthesis of ?- and ß-C-(1#3)-linked Disaccharides
  • Study Towards the Stereoselective Synthesis of ?- and ß-C-(1#3)-linked Disaccharides (en)
skos:notation
  • RIV/60461373:22330/01:00004250!RIV/2004/MSM/223304/N
http://linked.open.../vavai/riv/strany
  • 181
http://linked.open...avai/riv/aktivita
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  • Z(MSM 223300006)
http://linked.open...vai/riv/dodaniDat
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  • 697786
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  • RIV/60461373:22330/01:00004250
http://linked.open...riv/jazykVysledku
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  • C-glycosides;inhibitors;cycloaddition;stereoselectivity (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [EAD018FA1443]
http://linked.open...v/mistoKonaniAkce
  • Praha
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  • Neuveden
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  • 9th Meeting on Stereochemistry, Book of Abstracts
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  • Štěpánek, Petr
  • Šimák, Ondřej
  • Dvořáková, Hana
  • Kniežo, Ladislav
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
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  • Vysoká škola chemicko-technologická v Praze
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  • 80-7080-427-0
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  • 22330
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