About: Breakthrough characteristics of volatile organic compounds in the -10 to +170 degrees C temperature range on Tenax TA determined by microtrap technology     Goto   Sponge   NotDistinct   Permalink

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  • Není k dispozici (cs)
  • In this work the breakthrough volumes (BTVs) of volatile organic compounds (VOCs) on Tenax TA were determined in the - 10 to 170degreesC temperature range by using microtrap, (MT) technology. The MT technology allowed experimental investigation of the temperature dependence of BTVs. Along with the BTV data, we also discuss the thermodynamics of the temperature dependence of the BTV through a two-parameter equation In (BTV) = A(1) / T + C-1 where T is temperature (K), A(1) = -Delta H/R where DeltaH is enthalpy of sorption and C-1 is constant. This equation fitted well the experimental results with R-2 values between 0.9737 (acetone) and 0.9995 (dimethyl disulfide), with n between 6 and 11. However, for n-pentane, n-hexane and 1-hexene it proved that a three parameter equation In (BTV) = A(2)/ T + BTB + C-2 fitted better to the experimental results, with A(2) = -DeltaH(To)/R, B = DeltaC(P)/R, T-B = ln(T/T-O) + (T-O-T)/T, C-2 a constant, DeltaH(To) the adsorption enthalpy at reference temperature T-o and
  • In this work the breakthrough volumes (BTVs) of volatile organic compounds (VOCs) on Tenax TA were determined in the - 10 to 170degreesC temperature range by using microtrap, (MT) technology. The MT technology allowed experimental investigation of the temperature dependence of BTVs. Along with the BTV data, we also discuss the thermodynamics of the temperature dependence of the BTV through a two-parameter equation In (BTV) = A(1) / T + C-1 where T is temperature (K), A(1) = -Delta H/R where DeltaH is enthalpy of sorption and C-1 is constant. This equation fitted well the experimental results with R-2 values between 0.9737 (acetone) and 0.9995 (dimethyl disulfide), with n between 6 and 11. However, for n-pentane, n-hexane and 1-hexene it proved that a three parameter equation In (BTV) = A(2)/ T + BTB + C-2 fitted better to the experimental results, with A(2) = -DeltaH(To)/R, B = DeltaC(P)/R, T-B = ln(T/T-O) + (T-O-T)/T, C-2 a constant, DeltaH(To) the adsorption enthalpy at reference temperature T-o and (en)
Title
  • Breakthrough characteristics of volatile organic compounds in the -10 to +170 degrees C temperature range on Tenax TA determined by microtrap technology
  • Breakthrough characteristics of volatile organic compounds in the -10 to +170 degrees C temperature range on Tenax TA determined by microtrap technology (en)
  • Breakthrough characteristics of volatile organic compounds in the -10 to +170 degrees C temperature range on Tenax TA determined by microtrap technology (cs)
skos:prefLabel
  • Breakthrough characteristics of volatile organic compounds in the -10 to +170 degrees C temperature range on Tenax TA determined by microtrap technology
  • Breakthrough characteristics of volatile organic compounds in the -10 to +170 degrees C temperature range on Tenax TA determined by microtrap technology (en)
  • Breakthrough characteristics of volatile organic compounds in the -10 to +170 degrees C temperature range on Tenax TA determined by microtrap technology (cs)
skos:notation
  • RIV/60461373:22320/04:00011900!RIV/2005/MSM/223205/N
http://linked.open.../vavai/riv/strany
  • 215-223
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM 223200003)
http://linked.open...iv/cisloPeriodika
  • 1-2
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 556539
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22320/04:00011900
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • MONOCYCLIC AROMATIC-HYDROCARBONS;GAS-CHROMATOGRAPHY;RETENTION CHARACTERISTICS;ADSORPTION PROPERTIES;THERMAL-DESORPTION;ACTIVATED CARBONS;AIR;POLLUTANTS;EFFICIENCIES;ENRICHMENT (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [AA730A37D284]
http://linked.open...i/riv/nazevZdroje
  • Journal of Chromatography A
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 1038
http://linked.open...iv/tvurceVysledku
  • Víden, Ivan
  • Dewulf, Jo
  • Van Langenhove, Herman
  • Kroupa, Antonín
http://linked.open...n/vavai/riv/zamer
issn
  • 0021-9673
number of pages
http://localhost/t...ganizacniJednotka
  • 22320
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