About: Indene epoxidation over immobilized methyltrioxorhenium on MCM-41 silica, fumed silica and aluminosilicate materials

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About: Indene epoxidation over immobilized methyltrioxorhenium on MCM-41 silica, fumed silica and aluminosilicate materials Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The presented report focuses on the testing of heterogenized methyltrioxorhenium (MTO) in indene epoxidation. A range of mesoporous materials with different SiO2/Al2O3 ratios, namely aluminosilicates type Siral and MCM-41 silica and fumed silica, were used as supports for immobilization of MTO. The tested support materials and prepared catalytic systems exhibited high surface area, well-defined regular structure and narrow pore size distribution of mesopores and therefore represent good quality catalysts for various reactions. The immobilized MTO on various supports was tested for the preparation of 1,2-epoxyindane using two forms of hydrogen peroxide as oxidation agents, namely aqueous solution of hydrogen peroxide and its anhydrous form, urea-hydrogen peroxide. The prepared catalysts were successfully used for the preparation of 1,2-epoxyindane with achieved 100 % selectivities to the desired product at high conversions of indene. The presented report focuses on the testing of heterogenized methyltrioxorhenium (MTO) in indene epoxidation. A range of mesoporous materials with different SiO2/Al2O3 ratios, namely aluminosilicates type Siral and MCM-41 silica and fumed silica, were used as supports for immobilization of MTO. The tested support materials and prepared catalytic systems exhibited high surface area, well-defined regular structure and narrow pore size distribution of mesopores and therefore represent good quality catalysts for various reactions. The immobilized MTO on various supports was tested for the preparation of 1,2-epoxyindane using two forms of hydrogen peroxide as oxidation agents, namely aqueous solution of hydrogen peroxide and its anhydrous form, urea-hydrogen peroxide. The prepared catalysts were successfully used for the preparation of 1,2-epoxyindane with achieved 100 % selectivities to the desired product at high conversions of indene. (en)
Title	Indene epoxidation over immobilized methyltrioxorhenium on MCM-41 silica, fumed silica and aluminosilicate materials Indene epoxidation over immobilized methyltrioxorhenium on MCM-41 silica, fumed silica and aluminosilicate materials (en)
skos:prefLabel	Indene epoxidation over immobilized methyltrioxorhenium on MCM-41 silica, fumed silica and aluminosilicate materials Indene epoxidation over immobilized methyltrioxorhenium on MCM-41 silica, fumed silica and aluminosilicate materials (en)
skos:notation	RIV/60461373:22310/14:43897771!RIV15-MSM-22310___
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(ED2.1.00/03.0071)
http://linked.open...iv/cisloPeriodika	5
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Minaříková, Hana Červený, Libor Vyskočilová, Eliška Štekrová, Martina
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemické technologie
http://linked.open...dnocenehoVysledku	21164
http://linked.open...ai/riv/idVysledku	RIV/60461373:22310/14:43897771
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Hydrogen peroxide; Epoxidation; Indene; Methyltrioxorhenium (en)
http://linked.open.../riv/klicoveSlovo	Indene Methyltrioxorhenium Epoxidation Hydrogen peroxide
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[1182579373FF]
http://linked.open...i/riv/nazevZdroje	Journal of Porous Materials
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Unipetrol Centre of Research and Education
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	21
http://linked.open...iv/tvurceVysledku	Červený, Libor Vyskočilová, Eliška Štekrová, Martina Minaříková, Hana
http://linked.open...ain/vavai/riv/wos	000341840900027
issn	1380-2224
number of pages	11 (xsd:int)
http://bibframe.org/vocab/doi	10.1007/s10934-014-9822-7
http://localhost/t...ganizacniJednotka	22310

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