About: Model for photodegradation of polybrominated diphenyl ethers

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Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://link.springer.com/article/10.1007%2Fs11356-014-3741-7
Description	Polybrominated diphenyl ethers (PBDE) were, and in some countries still are, used as flame retardants for plastic materials. When released from plastics, PDBE cause harm to the environment. This creates the incentive for further inves- tigation of the PBDE degradation. This work focused on a formulation of a PBDE photodegradation model based on the PBDE properties obtained by the quantum chemical calcula- tions. The proposed model predicted degradation routes of arbitrary PBDE congener. The routes of selected congeners were validated by the two independently published data sets and showed the high fitting degree. The model can be easily modified for any reactor system if the initial reaction rate constant of one congener is available for the given system. Polybrominated diphenyl ethers (PBDE) were, and in some countries still are, used as flame retardants for plastic materials. When released from plastics, PDBE cause harm to the environment. This creates the incentive for further inves- tigation of the PBDE degradation. This work focused on a formulation of a PBDE photodegradation model based on the PBDE properties obtained by the quantum chemical calcula- tions. The proposed model predicted degradation routes of arbitrary PBDE congener. The routes of selected congeners were validated by the two independently published data sets and showed the high fitting degree. The model can be easily modified for any reactor system if the initial reaction rate constant of one congener is available for the given system. (en)
Title	Model for photodegradation of polybrominated diphenyl ethers Model for photodegradation of polybrominated diphenyl ethers (en)
skos:prefLabel	Model for photodegradation of polybrominated diphenyl ethers Model for photodegradation of polybrominated diphenyl ethers (en)
skos:notation	RIV/60461373:22310/14:43897663!RIV15-GA0-22310___
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(GAP105/12/0664)
http://linked.open...iv/cisloPeriodika	říjen
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Veselý, Martin
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemické technologie
http://linked.open...dnocenehoVysledku	29710
http://linked.open...ai/riv/idVysledku	RIV/60461373:22310/14:43897663
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Polybrominated diphenyl ethers . Photodegradation model . Quantum chemical calculation (en)
http://linked.open.../riv/klicoveSlovo	Polybrominated diphenyl ethers . Photodegradation model . Quantum chemical calculation
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[D97C0FA831D5]
http://linked.open...i/riv/nazevZdroje	Environmental Science and Pollution Research
http://linked.open...in/vavai/riv/obor	CH
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Hydro-mechanical interactions of particles in solid-fluid systems
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	neuveden
http://linked.open...iv/tvurceVysledku	Jiřičný, Vladimír Ponec, Robert Kotas, Petr Vajglová, Zuzana Křišťál, Jiří Veselý, Martin
issn	0944-1344
number of pages	15 (xsd:int)
http://bibframe.org/vocab/doi	10.1007/s11356-014-3741-7
http://localhost/t...ganizacniJednotka	22310

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