About: Surface morphology and optical properties of porphyrin/Au and Au/porphyrin/Au systems     Goto   Sponge   NotDistinct   Permalink

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  • Porphyrin/Au and Au/porphyrin/Au systems were prepared by vacuum evaporation and vacuum sputtering onto glass substrate. The surface morphology of as-prepared systems and those subjected to annealing at 160A degrees C was studied by optical microscopy, atomic force microscopy, and scanning electron microscopy techniques. Absorption and luminescence spectra of as-prepared and annealed samples were measured. Annealing leads to disintegration of the initially continuous gold layer and formation of gold nanoclusters. An amplification of Soret band magnitude was observed on the Au/meso-tetraphenyl porphyrin (TPP) system in comparison with mere TPP. Additional enhancement of luminescence was observed after the sample annealing. In the case of sandwich Au/porphyrin/Au structure, suppression of one of the two porphyrins' luminescence maxima and sufficient enhancement of the second one were observed.
  • Porphyrin/Au and Au/porphyrin/Au systems were prepared by vacuum evaporation and vacuum sputtering onto glass substrate. The surface morphology of as-prepared systems and those subjected to annealing at 160A degrees C was studied by optical microscopy, atomic force microscopy, and scanning electron microscopy techniques. Absorption and luminescence spectra of as-prepared and annealed samples were measured. Annealing leads to disintegration of the initially continuous gold layer and formation of gold nanoclusters. An amplification of Soret band magnitude was observed on the Au/meso-tetraphenyl porphyrin (TPP) system in comparison with mere TPP. Additional enhancement of luminescence was observed after the sample annealing. In the case of sandwich Au/porphyrin/Au structure, suppression of one of the two porphyrins' luminescence maxima and sufficient enhancement of the second one were observed. (en)
Title
  • Surface morphology and optical properties of porphyrin/Au and Au/porphyrin/Au systems
  • Surface morphology and optical properties of porphyrin/Au and Au/porphyrin/Au systems (en)
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  • Surface morphology and optical properties of porphyrin/Au and Au/porphyrin/Au systems
  • Surface morphology and optical properties of porphyrin/Au and Au/porphyrin/Au systems (en)
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  • RIV/60461373:22310/13:43895867!RIV14-GA0-22310___
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  • I, P(GAP108/12/1168), P(GPP108/11/P840)
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  • 547
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  • 109091
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  • RIV/60461373:22310/13:43895867
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  • Surface morphology; Enhancement; Luminescence; Porphyrin; Gold; Nanostructures (en)
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  • US - Spojené státy americké
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  • [CFA964799318]
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  • Nanoscale Research Letters
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  • 8
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  • Lyutakov, Oleksiy
  • Slepička, Petr
  • Švorčík, Václav
  • Kalachyova, Yevgeniya
  • Solovyev, Andrey
http://linked.open...ain/vavai/riv/wos
  • 000329945500001
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  • 1931-7573
number of pages
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  • 10.1186/1556-276X-8-547
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  • 22310
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