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Description
| - Butyl 3-bromo-3H-diazirine-3-carboxylate (7) and 3-bromo-3-phenyl-3H-diazirine exhibit nitrenic reactivity with phenylmagnesium bromide or tetrabutylammonium cyanide. The formation of several N,N?-disubstituted amidines is attributed to the intermediacy of 1-phenyl or 1-cyano-1H-diazirines possessing a singlet imidoylnitrene character at the N2 atom. Most notably, the reaction of 7 with PhMgBr in diethyl ether affords 2-hydroxy-2,2,N-triphenylacetamidine and 2-methyl-5,5-diphenyl-4-phenylamino-2,5-dihydrooxazole, products derived from nitrene insertion to the alpha-C?H bond of ether.
- Butyl 3-bromo-3H-diazirine-3-carboxylate (7) and 3-bromo-3-phenyl-3H-diazirine exhibit nitrenic reactivity with phenylmagnesium bromide or tetrabutylammonium cyanide. The formation of several N,N?-disubstituted amidines is attributed to the intermediacy of 1-phenyl or 1-cyano-1H-diazirines possessing a singlet imidoylnitrene character at the N2 atom. Most notably, the reaction of 7 with PhMgBr in diethyl ether affords 2-hydroxy-2,2,N-triphenylacetamidine and 2-methyl-5,5-diphenyl-4-phenylamino-2,5-dihydrooxazole, products derived from nitrene insertion to the alpha-C?H bond of ether. (en)
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Title
| - Nitrenic reactivity of diazirines
- Nitrenic reactivity of diazirines (en)
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skos:prefLabel
| - Nitrenic reactivity of diazirines
- Nitrenic reactivity of diazirines (en)
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skos:notation
| - RIV/60461373:22310/13:43895609!RIV14-MSM-22310___
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http://linked.open...avai/predkladatel
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/60461373:22310/13:43895609
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - nitrene C?H insertion; imidoylnitrenes; 1H-diazirines; 3H-diazirines (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Martinů, Tomáš
- Linhart, Igor
- Kolářová, Petra
- Álvarez Martínez, Ignacio
- Čmolík, Václav
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1016/j.tetlet.2013.10.001
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http://localhost/t...ganizacniJednotka
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