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  • Fe-Al alloys have been known for more than 100 years. Their exceptional oxidation and sulphidation resistance makes them promising for many industrial applications. However, these materials suffer from poor room-temperature ductility and problems during a production by conventional melting metallurgy. Therefore, reactive sintering of iron and aluminium compressed powder mixtures have been proposed as the alternative technology of their production. Unfortunately, this production technology leads to highly porous products. There are many theories why the porosity is so high and all of them deal with the intermetallic phases' formation mechanisms. There are at least three different phases' formation sequences during heating described in the literature. In this work, the in situ high energy X-ray diffraction analysis was carried out during the reactive sintering process and the mechanism of the formation of intermetallics in FeAl25 powder mixture was described during isothermal annealing at 800°C as well as during a slow continuous heating to this temperature. In both cases, no phases are formed prior the melting of aluminium particles. After that, Fe2Al5 and FeAl phases arise. The effect of the intermetallics' formation on the porosity of Fe-Al alloys is discussed.
  • Fe-Al alloys have been known for more than 100 years. Their exceptional oxidation and sulphidation resistance makes them promising for many industrial applications. However, these materials suffer from poor room-temperature ductility and problems during a production by conventional melting metallurgy. Therefore, reactive sintering of iron and aluminium compressed powder mixtures have been proposed as the alternative technology of their production. Unfortunately, this production technology leads to highly porous products. There are many theories why the porosity is so high and all of them deal with the intermetallic phases' formation mechanisms. There are at least three different phases' formation sequences during heating described in the literature. In this work, the in situ high energy X-ray diffraction analysis was carried out during the reactive sintering process and the mechanism of the formation of intermetallics in FeAl25 powder mixture was described during isothermal annealing at 800°C as well as during a slow continuous heating to this temperature. In both cases, no phases are formed prior the melting of aluminium particles. After that, Fe2Al5 and FeAl phases arise. The effect of the intermetallics' formation on the porosity of Fe-Al alloys is discussed. (en)
Title
  • Formation of Intermetallics during Reactive Sintering Production of Fe-Al Alloys
  • Formation of Intermetallics during Reactive Sintering Production of Fe-Al Alloys (en)
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  • Formation of Intermetallics during Reactive Sintering Production of Fe-Al Alloys
  • Formation of Intermetallics during Reactive Sintering Production of Fe-Al Alloys (en)
skos:notation
  • RIV/60461373:22310/12:43894306!RIV15-GA0-22310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GBP108/12/G043)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 136997
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22310/12:43894306
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • XRD; reactive sintering; iron aluminide (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [CE5BFFC030B8]
http://linked.open...v/mistoKonaniAkce
  • Brno
http://linked.open...i/riv/mistoVydani
  • Ostrava
http://linked.open...i/riv/nazevZdroje
  • Proceedings of 21st International Conference on Metallurgy and Materials
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Marek, Ivo
  • Mudrová, Martina
  • Novák, Pavel
  • Michalcová, Alena
  • Saksl, Karel
  • Bednarčík, Josef
http://linked.open...vavai/riv/typAkce
http://linked.open...ain/vavai/riv/wos
  • 000318506500200
http://linked.open.../riv/zahajeniAkce
number of pages
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  • Tanger s.r.o.
https://schema.org/isbn
  • 978-80-87294-29-1
http://localhost/t...ganizacniJednotka
  • 22310
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