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  • Electrochemical applications of graphene are of great interest to many researchers as they can potentially lead to crucial technological advancements in fabrication of electrochemical devices for energy production and storage, and highly sensitive sensors. There are many routes towards fabrication of bulk quantities of chemically modified graphenes (CMG) for applications such as electrode materials. Each of them yields different graphene materials with different functionalities and structural defects. Here, we compare the electrochemical properties of five different chemically modified graphenes: graphite oxide, graphene oxide, thermally reduced graphene oxide, chemically reduced graphene oxide, and electrochemically reduced graphene oxide. We characterized these materials using transmission electron microscopy, Raman spectroscopy, high-resolution X-ray photoelectron spectroscopy, electrochemical impedance spectroscopy, and cyclic voltammetry, which allowed us to correlate the electrochemical properties with the structural and chemical features of the CMGs. We found that thermally reduced graphene oxide offers the most favorable electrochemical performance among the different materials studied. Our findings have a profound impact for the applications of chemically modified graphenes in electrochemical devices.
  • Electrochemical applications of graphene are of great interest to many researchers as they can potentially lead to crucial technological advancements in fabrication of electrochemical devices for energy production and storage, and highly sensitive sensors. There are many routes towards fabrication of bulk quantities of chemically modified graphenes (CMG) for applications such as electrode materials. Each of them yields different graphene materials with different functionalities and structural defects. Here, we compare the electrochemical properties of five different chemically modified graphenes: graphite oxide, graphene oxide, thermally reduced graphene oxide, chemically reduced graphene oxide, and electrochemically reduced graphene oxide. We characterized these materials using transmission electron microscopy, Raman spectroscopy, high-resolution X-ray photoelectron spectroscopy, electrochemical impedance spectroscopy, and cyclic voltammetry, which allowed us to correlate the electrochemical properties with the structural and chemical features of the CMGs. We found that thermally reduced graphene oxide offers the most favorable electrochemical performance among the different materials studied. Our findings have a profound impact for the applications of chemically modified graphenes in electrochemical devices. (en)
Title
  • Electrochemistry at Chemically Modified Graphenes
  • Electrochemistry at Chemically Modified Graphenes (en)
skos:prefLabel
  • Electrochemistry at Chemically Modified Graphenes
  • Electrochemistry at Chemically Modified Graphenes (en)
skos:notation
  • RIV/60461373:22310/11:43892064!RIV12-MSM-22310___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA104/09/0621), Z(MSM6046137302)
http://linked.open...iv/cisloPeriodika
  • 38
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 197049
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22310/11:43892064
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • graphene oxide; graphene; electrochemistry; chemically modified graphenes (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [7045B7D7C0CB]
http://linked.open...i/riv/nazevZdroje
  • Chemistry A European Journal
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 17
http://linked.open...iv/tvurceVysledku
  • Bonanni, Alessandra
  • Pumera, Martin
  • Sofer, Zdeněk
  • Ambrosi, Adriano
  • Cross, Jeffrey S.
http://linked.open...ain/vavai/riv/wos
  • 000295880300034
http://linked.open...n/vavai/riv/zamer
issn
  • 0947-6539
number of pages
http://bibframe.org/vocab/doi
  • 10.1002/chem.201101117
http://localhost/t...ganizacniJednotka
  • 22310
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