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  • Heat capacity and enthalpy increments of ternary bismuth tantalum oxides Bi(4)Ta(2)O(11), Bi(7)Ta(3)O(18) and Bi(3)TaO(7) were measured by the relaxation time method (2-280 K), DSC (265-353 K) and drop calorimetry (622-1322 K). Temperature dependencies of the molar heat capacity in the form C(pm)=445.8 + 0.005451T-7.489 x 10(6)/T(2) J K(-1) mo1(-1), C(pm)= 699.0+0.05276T-9.956 x 10(6)/T(2) J K(-1) mol(-1) and C(pm) =251.6+0.06705T-3.237 x 10(6)/T(2) J K(-1) mol(-1) for Bi(3)TaO(7), Bi(4)Ta(2)O(11) and for Bi(7)Ta(3)O(18), respectively, were derived by the least-squares method from the experimental data. The molar entropies at 298.15 K,S degrees(m)(298.15 K)= 449.6 +/- 2.3 J K(-1) mol(-1) for Bi(4)Ta(2)O(11), S degrees(m)(298.15 K)= 743.0 +/- 3.8 J K(-1) mol(-1) for Bi(7)Ta(3)O(18) and S degrees(m)(298.15K)= 304.3 +/- 1.6 J K(-1) mol(-1) for Bi(3)TaO(7), were evaluated from the low-temperature heat capacity measurements.
  • Heat capacity and enthalpy increments of ternary bismuth tantalum oxides Bi(4)Ta(2)O(11), Bi(7)Ta(3)O(18) and Bi(3)TaO(7) were measured by the relaxation time method (2-280 K), DSC (265-353 K) and drop calorimetry (622-1322 K). Temperature dependencies of the molar heat capacity in the form C(pm)=445.8 + 0.005451T-7.489 x 10(6)/T(2) J K(-1) mo1(-1), C(pm)= 699.0+0.05276T-9.956 x 10(6)/T(2) J K(-1) mol(-1) and C(pm) =251.6+0.06705T-3.237 x 10(6)/T(2) J K(-1) mol(-1) for Bi(3)TaO(7), Bi(4)Ta(2)O(11) and for Bi(7)Ta(3)O(18), respectively, were derived by the least-squares method from the experimental data. The molar entropies at 298.15 K,S degrees(m)(298.15 K)= 449.6 +/- 2.3 J K(-1) mol(-1) for Bi(4)Ta(2)O(11), S degrees(m)(298.15 K)= 743.0 +/- 3.8 J K(-1) mol(-1) for Bi(7)Ta(3)O(18) and S degrees(m)(298.15K)= 304.3 +/- 1.6 J K(-1) mol(-1) for Bi(3)TaO(7), were evaluated from the low-temperature heat capacity measurements. (en)
Title
  • Heat capacity, enthalpy and entropy of ternary bismuth tantalum oxides
  • Heat capacity, enthalpy and entropy of ternary bismuth tantalum oxides (en)
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  • Heat capacity, enthalpy and entropy of ternary bismuth tantalum oxides
  • Heat capacity, enthalpy and entropy of ternary bismuth tantalum oxides (en)
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  • RIV/60461373:22310/11:43880125!RIV12-MSM-22310___
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  • P(GA104/07/1209), P(GAP108/10/1006), Z(MSM0021620834), Z(MSM6046137302), Z(MSM6046137307)
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  • 2
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  • 201809
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  • RIV/60461373:22310/11:43880125
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  • Bismuth tantalate; Calorimetry; Entropy; Heat capacity; Enthalpy increments (en)
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  • NL - Nizozemsko
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  • [E0E4BF986149]
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  • J. Solid State Chem.
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  • 184
http://linked.open...iv/tvurceVysledku
  • Růžička, Květoslav
  • Sofer, Zdeněk
  • Svoboda, Pavel
  • Leitner, Jindřich
  • Sedmidubský, David
  • Jakeš, Vít
http://linked.open...ain/vavai/riv/wos
  • 000287268900003
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  • 0022-4596
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  • 10.1016/j.jssc.2010.11.020
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  • 22310
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