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Description
  • Thiacalix[4]arene immobilized in the cone conformation undergoes a direct formylation reaction giving unusual products in high yields. The Duff reaction (urotropine/TFA) leads to unprecedented intra-molecularly bridged compounds possessing two formyl groups on the opposite para- or para-/meta- positions. The comparison with the corresponding classical calix[4]arene analogues indicates an amazingly different reactivity of the thiacalix[4]arene system.
  • Thiacalix[4]arene immobilized in the cone conformation undergoes a direct formylation reaction giving unusual products in high yields. The Duff reaction (urotropine/TFA) leads to unprecedented intra-molecularly bridged compounds possessing two formyl groups on the opposite para- or para-/meta- positions. The comparison with the corresponding classical calix[4]arene analogues indicates an amazingly different reactivity of the thiacalix[4]arene system. (en)
Title
  • Unusual Intramolecular Bridging Reaction in Thiacalix[4]arene Series
  • Unusual Intramolecular Bridging Reaction in Thiacalix[4]arene Series (en)
skos:prefLabel
  • Unusual Intramolecular Bridging Reaction in Thiacalix[4]arene Series
  • Unusual Intramolecular Bridging Reaction in Thiacalix[4]arene Series (en)
skos:notation
  • RIV/60461373:22310/09:00022820!RIV10-GA0-22310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/09/0691), P(IAAX08240901)
http://linked.open...iv/cisloPeriodika
  • 18
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 347681
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22310/09:00022820
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • calixarene; formylation; synthesis; NMR assignment (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [DBF9979F079E]
http://linked.open...i/riv/nazevZdroje
  • Organic Letters
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 11
http://linked.open...iv/tvurceVysledku
  • Císařová, Ivana
  • Pojarová, Michaela
  • Dvořáková, Hana
  • Kundrát, Ondřej
  • Lhoták, Pavel
http://linked.open...ain/vavai/riv/wos
  • 000269670700041
issn
  • 1523-7060
number of pages
http://localhost/t...ganizacniJednotka
  • 22310
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