About: Heat Capacity, Enthalpy and Entropy of Bismuth Strontium Niobate and Bismuth Strontium Tantalate     Goto   Sponge   NotDistinct   Permalink

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Description
  • Tepelné kapacity a přírůstky entalpie SrBi2Nb2O9 (SBN) a SrBi2Ta2O9 (SBT) byly měřeny relaxační metodou (2-150 K), kalorimetrií Calvetova typu (305-570 K) a vhazovací kalorimetrií (773-1373 K). (cs)
  • The heat capacities and enthalpy increments of strontium bismuth niobate SrBi2Nb2O9 (SBN) and strontium bismuth tantalate SrBi2Ta2O9 (SBT) were measured by the relaxation method (2-150 K), Calvet-type heat-conduction calorimetry (305-570 K) and drop calorimetry (773-1373 K). The temperature dependences of non-transition heat capacities in the form Cpm = 324.47 + 0.06371T −5.0755x106/T2 JK−1 mol−1 (298-1400 K) and Cpm = 320.22 + 0.06451T−4.7001x106/T2 JK−1 mol−1 (298-1400 K) were derived for SBN and SBT, respectively, by the least-squares method from the experimental data. Furthermore, the standard molar entropies at 298.15K S◦m (SBN) = 327.15 +/- 0.80 and S◦m (SBT) = 339.23 +/- 0.72 JK−1 mol−1 were evaluated from the low-temperature heat capacity measurements.
  • The heat capacities and enthalpy increments of strontium bismuth niobate SrBi2Nb2O9 (SBN) and strontium bismuth tantalate SrBi2Ta2O9 (SBT) were measured by the relaxation method (2-150 K), Calvet-type heat-conduction calorimetry (305-570 K) and drop calorimetry (773-1373 K). The temperature dependences of non-transition heat capacities in the form Cpm = 324.47 + 0.06371T −5.0755x106/T2 JK−1 mol−1 (298-1400 K) and Cpm = 320.22 + 0.06451T−4.7001x106/T2 JK−1 mol−1 (298-1400 K) were derived for SBN and SBT, respectively, by the least-squares method from the experimental data. Furthermore, the standard molar entropies at 298.15K S◦m (SBN) = 327.15 +/- 0.80 and S◦m (SBT) = 339.23 +/- 0.72 JK−1 mol−1 were evaluated from the low-temperature heat capacity measurements. (en)
Title
  • Heat Capacity, Enthalpy and Entropy of Bismuth Strontium Niobate and Bismuth Strontium Tantalate
  • Tepelná kapacita, entalpie a entropie niobičnanu a tantaličnanu bizmutito-strontnatého (cs)
  • Heat Capacity, Enthalpy and Entropy of Bismuth Strontium Niobate and Bismuth Strontium Tantalate (en)
skos:prefLabel
  • Heat Capacity, Enthalpy and Entropy of Bismuth Strontium Niobate and Bismuth Strontium Tantalate
  • Tepelná kapacita, entalpie a entropie niobičnanu a tantaličnanu bizmutito-strontnatého (cs)
  • Heat Capacity, Enthalpy and Entropy of Bismuth Strontium Niobate and Bismuth Strontium Tantalate (en)
skos:notation
  • RIV/60461373:22310/06:00017674!RIV07-MSM-22310___
http://linked.open.../vavai/riv/strany
  • 105-109
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM6046137302)
http://linked.open...iv/cisloPeriodika
  • 450
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 477507
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22310/06:00017674
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • niobates; tantalates; heat capacity; relative enthalpy; thermochemical properties (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • IE - Irsko
http://linked.open...ontrolniKodProRIV
  • [62BB2A434ADA]
http://linked.open...i/riv/nazevZdroje
  • Thermochimica Acta
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Růžička, Květoslav
  • Svoboda, Petr
  • Leitner, Jindřich
  • Sedmidubský, David
  • Vejpravová, Jana
  • Hampl, Milan
http://linked.open...n/vavai/riv/zamer
issn
  • 0040-6031
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  • 22310
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