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  • The selected pseudobinary, isothermal and isoactivity sections of the Bi2O3-SrO-MnOx phase diagram are constructed from the calculated phase equilibria. The starting point for the thermodynamic analysis were the assessments of the respective pseudobinary systems Bi2O3-SrO, Bi2O3-MnOx and SrO-MnOx. The only quaternary solid phase-the perovskite solid solution-is described in terms of the point defect model [Bi3+1−xSr2+x][Mn3+1−x+2gama Mn4+x−2gama] [O2−1−gama/3 Va gama/3]3. The quaternary liquid is approximated by a phenomenological model using the liquid species Mn, MnO, MnO1.5, SrO, and BiO1.5 with only binary Redlich-Kister coefficients. The ab initio electronic structure calculations of cohesive energies are employed to evaluate the enthalpies of formation of some stoichiometric phases.
  • The selected pseudobinary, isothermal and isoactivity sections of the Bi2O3-SrO-MnOx phase diagram are constructed from the calculated phase equilibria. The starting point for the thermodynamic analysis were the assessments of the respective pseudobinary systems Bi2O3-SrO, Bi2O3-MnOx and SrO-MnOx. The only quaternary solid phase-the perovskite solid solution-is described in terms of the point defect model [Bi3+1−xSr2+x][Mn3+1−x+2gama Mn4+x−2gama] [O2−1−gama/3 Va gama/3]3. The quaternary liquid is approximated by a phenomenological model using the liquid species Mn, MnO, MnO1.5, SrO, and BiO1.5 with only binary Redlich-Kister coefficients. The ab initio electronic structure calculations of cohesive energies are employed to evaluate the enthalpies of formation of some stoichiometric phases. (en)
  • Vybrané pseudobinární, izotermální a izoaktivitní sekce fázového diagramu Bi2O3-SrO-MnOx byly zkonstruovány z vypočtených fázových rovnováh. (cs)
Title
  • Phase Equilibria Modeling in Bi-Sr-Mn-O System
  • Phase Equilibria Modeling in Bi-Sr-Mn-O System (en)
  • Modelování fázových rovnováh v systému Bi-Sr-Mn-O (cs)
skos:prefLabel
  • Phase Equilibria Modeling in Bi-Sr-Mn-O System
  • Phase Equilibria Modeling in Bi-Sr-Mn-O System (en)
  • Modelování fázových rovnováh v systému Bi-Sr-Mn-O (cs)
skos:notation
  • RIV/60461373:22310/06:00017000!RIV07-MSM-22310___
http://linked.open.../vavai/riv/strany
  • 179-184
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/03/0924), Z(MSM6046137302)
http://linked.open...iv/cisloPeriodika
  • 2
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 491954
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22310/06:00017000
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • bismuth manganites; phase diagrams; thermodynamic modeling (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • IE - Irsko
http://linked.open...ontrolniKodProRIV
  • [262A3E64494B]
http://linked.open...i/riv/nazevZdroje
  • CALPHAD
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 30
http://linked.open...iv/tvurceVysledku
  • Beneš, Ondřej
  • Leitner, Jindřich
  • Sedmidubský, David
http://linked.open...n/vavai/riv/zamer
issn
  • 0364-5916
number of pages
http://localhost/t...ganizacniJednotka
  • 22310
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