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  • It was found that the flavin-zinc(II)-cyclen derivative 1a catalyzed efficiently photoinduced electron-transfer oxidation of 4-methoxybenzyl alcohol in acetonitril under atmospheric pressure of oxygen. After reduction by sodium dithionite and after irradiation, reduced molecule 1b cleaved thymine dimer. In these reactions, presence of the covalently bound zinc(II)-cyclen subunit is crucial for efficient functioning of our photocatalysts. Photooxidations by water soluble derivative 1 were also tested in aqueous solutions.
  • It was found that the flavin-zinc(II)-cyclen derivative 1a catalyzed efficiently photoinduced electron-transfer oxidation of 4-methoxybenzyl alcohol in acetonitril under atmospheric pressure of oxygen. After reduction by sodium dithionite and after irradiation, reduced molecule 1b cleaved thymine dimer. In these reactions, presence of the covalently bound zinc(II)-cyclen subunit is crucial for efficient functioning of our photocatalysts. Photooxidations by water soluble derivative 1 were also tested in aqueous solutions. (en)
Title
  • Light-driven catalysts based on flavin-zinc(II)-cyclen system
  • Light-driven catalysts based on flavin-zinc(II)-cyclen system (en)
skos:prefLabel
  • Light-driven catalysts based on flavin-zinc(II)-cyclen system
  • Light-driven catalysts based on flavin-zinc(II)-cyclen system (en)
skos:notation
  • RIV/60461373:22310/03:00007917!RIV/2004/MSM/223104/N
http://linked.open.../vavai/riv/strany
  • 29;29
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM 223100001)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 613546
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22310/03:00007917
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • electron transfer; photooxidation; cyclen; flavin (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [7E4C0B239C3C]
http://linked.open...v/mistoKonaniAkce
  • Walberberg, Germany
http://linked.open...i/riv/mistoVydani
  • Köln
http://linked.open...i/riv/nazevZdroje
  • Intra and Intermolecular Transfer
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Cibulka, Radek
  • König, B.
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
http://purl.org/ne...btex#hasPublisher
  • Universität Köln
http://localhost/t...ganizacniJednotka
  • 22310
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