About: Electroreduction of methyl azinyl ketoximes and their Ni(II), Cu(II) and Zn(II) complexes on mercury - correlation with their hydrolytic activity     Goto   Sponge   NotDistinct   Permalink

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  • Electroreduction of five azinyl methyl ketoximes and their Ni(II), Cu(II) and Zn(II) complexes was investigated polarographically and correlated with acidity of the hydroxyimino group, nucleophilicity of dissociated oximate anion and with hydrolytic activity towards model substrate (p-nitrophenyl acetate). Three different types of reduction of chelates were observed and their influence on the catalytic activity discussed.
  • Electroreduction of five azinyl methyl ketoximes and their Ni(II), Cu(II) and Zn(II) complexes was investigated polarographically and correlated with acidity of the hydroxyimino group, nucleophilicity of dissociated oximate anion and with hydrolytic activity towards model substrate (p-nitrophenyl acetate). Three different types of reduction of chelates were observed and their influence on the catalytic activity discussed. (en)
Title
  • Electroreduction of methyl azinyl ketoximes and their Ni(II), Cu(II) and Zn(II) complexes on mercury - correlation with their hydrolytic activity
  • Electroreduction of methyl azinyl ketoximes and their Ni(II), Cu(II) and Zn(II) complexes on mercury - correlation with their hydrolytic activity (en)
skos:prefLabel
  • Electroreduction of methyl azinyl ketoximes and their Ni(II), Cu(II) and Zn(II) complexes on mercury - correlation with their hydrolytic activity
  • Electroreduction of methyl azinyl ketoximes and their Ni(II), Cu(II) and Zn(II) complexes on mercury - correlation with their hydrolytic activity (en)
skos:notation
  • RIV/60461373:22310/02:00006514!RIV/2004/MSM/223104/N
http://linked.open.../vavai/riv/strany
  • 142-146
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM 223100001)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 644815
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22310/02:00006514
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • oxime; complexes; polarography; electroreduction; ester hydrolysis (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [A9E210B8014E]
http://linked.open...v/mistoKonaniAkce
  • Philadelphia, USA
http://linked.open...i/riv/mistoVydani
  • Philadelphia
http://linked.open...i/riv/nazevZdroje
  • Proceedings of the Fifth International Manuel M. Baizer Symposium in Honor of Professor Jean Michel Saveant,
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Cibulka, Radek
  • Ludvík, Jiří
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
http://purl.org/ne...btex#hasPublisher
  • The Electrochemical Society
http://localhost/t...ganizacniJednotka
  • 22310
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