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Description
| - Polymerization of adsorbed monomers at the water 1,2-dichloroethane interface was studied with a series of surface active derivatives of pyrrole. Polymerization was induced by an electron transfer reaction between a monomer dissolved in the organic phase and Ce(SO)4 dissolved in the aqueous phase. The formation of a polymer layer at the interface was monitored by surface tension measurement and by cyclic voltammetry in the presence of transferable ions. It was found that in contrast to a simple adsorbed layer, an interfacial tension in the presence of a polymer layer becomes independent of the applied potential and that a polymer layer strongly inhibits ion transfer reactions.
- Polymerization of adsorbed monomers at the water 1,2-dichloroethane interface was studied with a series of surface active derivatives of pyrrole. Polymerization was induced by an electron transfer reaction between a monomer dissolved in the organic phase and Ce(SO)4 dissolved in the aqueous phase. The formation of a polymer layer at the interface was monitored by surface tension measurement and by cyclic voltammetry in the presence of transferable ions. It was found that in contrast to a simple adsorbed layer, an interfacial tension in the presence of a polymer layer becomes independent of the applied potential and that a polymer layer strongly inhibits ion transfer reactions. (en)
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Title
| - Formation of a polymer layer from monomers adsorbed at a liquid vertical bar liquid interface
- Formation of a polymer layer from monomers adsorbed at a liquid vertical bar liquid interface (en)
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skos:prefLabel
| - Formation of a polymer layer from monomers adsorbed at a liquid vertical bar liquid interface
- Formation of a polymer layer from monomers adsorbed at a liquid vertical bar liquid interface (en)
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skos:notation
| - RIV/60461373:22310/01:00004399!RIV/2004/MSM/223104/N
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/60461373:22310/01:00004399
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - immiscible electrolyte solutions; adsorption; polymerization; polymer layer (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Journal of Electroanalytical chemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...ocetUcastnikuAkce
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http://linked.open...nichUcastnikuAkce
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Budka, Jan
- Mareček, Vladimír
- Stibor, Ivan
- Lhotský, Alexandr
- Jenchenová, Hana
- Meada, Kohji
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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