About: Tetrabutylammonium Butyldifluorodimethylsilicate and Difluorodimethylphenylsilicate, New Nucleophilic Fluorinating Reagents.     Goto   Sponge   NotDistinct   Permalink

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Description
  • Tetrabutylammonium butyldifluorodimethylsilicate (TAMBS, 1a) and tetrabutylammonium difluorodimethylphenylsilicate (TAMPS, 1b) were conveniently prepared from the corresponding substituted fluorodimethylsilanes and tetrabutylammonium fluoride. Both fluorosilicates 1a, 1b are powerful nucleophilic fluorinating reagents which transform primary or secondary halides, tosylates, or mesylates to the corresponding fluorides in moderate to good yields.
  • Tetrabutylammonium butyldifluorodimethylsilicate (TAMBS, 1a) and tetrabutylammonium difluorodimethylphenylsilicate (TAMPS, 1b) were conveniently prepared from the corresponding substituted fluorodimethylsilanes and tetrabutylammonium fluoride. Both fluorosilicates 1a, 1b are powerful nucleophilic fluorinating reagents which transform primary or secondary halides, tosylates, or mesylates to the corresponding fluorides in moderate to good yields. (en)
Title
  • Tetrabutylammonium Butyldifluorodimethylsilicate and Difluorodimethylphenylsilicate, New Nucleophilic Fluorinating Reagents.
  • Tetrabutylammonium Butyldifluorodimethylsilicate and Difluorodimethylphenylsilicate, New Nucleophilic Fluorinating Reagents. (en)
skos:prefLabel
  • Tetrabutylammonium Butyldifluorodimethylsilicate and Difluorodimethylphenylsilicate, New Nucleophilic Fluorinating Reagents.
  • Tetrabutylammonium Butyldifluorodimethylsilicate and Difluorodimethylphenylsilicate, New Nucleophilic Fluorinating Reagents. (en)
skos:notation
  • RIV/60461373:22310/01:00004332!RIV/2004/MSM/223104/N
http://linked.open.../vavai/riv/strany
  • 547-549
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM 223100001)
http://linked.open...iv/cisloPeriodika
  • 4
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
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http://linked.open...dnocenehoVysledku
  • 698620
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22310/01:00004332
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http://linked.open.../riv/klicovaSlova
  • nucleophilic fluorination, hypervalent silicon compounds, butyldifluorodimethylsilicate, difluorodimethylphenylsilicate (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [8E6C9CD77435]
http://linked.open...i/riv/nazevZdroje
  • Synlett
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http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • N
http://linked.open...iv/tvurceVysledku
  • Kvíčala, Jaroslav
  • Paleta, Oldřich
  • Mysík, Petr
http://linked.open...n/vavai/riv/zamer
issn
  • 0936-5214
number of pages
http://localhost/t...ganizacniJednotka
  • 22310
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