About: Planar Ni(II) 1,2-dithiolenes involving bidentate P-donor ligands

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A series of planar Ni(II) dithiolenes derived of maleonitriledithiol (mnt), benzene-1,2-dithiol (bdt) and toluene-3,4-dithiol (tdt) with bidentate P,P-ligands (dppe = 1,2-bis(diphenylphosphino)ethane, dppp = 1,3-bis(diphenylphosphino)propane, dppb = 1,4-bis(diphenylphosphino)butane, dpppn = 1,5-bis(diphenylphosphino)pentane) of the [Ni(P,P)(dithiol)] type have been synthesized. The compounds have been characterized by elemental analysis, IR and electronic spectroscopies, magnetochemical, conductivity measurements and thermal analysis. Single crystal X-ray analysis of [Ni(dpppn)(mnt)] confirmed a planar geometry of NiP2S2 chromophore. Possible practical applications such as use of these compounds for vulcanization accelerators and their anticholinesterase activity were evaluated. A series of planar Ni(II) dithiolenes derived of maleonitriledithiol (mnt), benzene-1,2-dithiol (bdt) and toluene-3,4-dithiol (tdt) with bidentate P,P-ligands (dppe = 1,2-bis(diphenylphosphino)ethane, dppp = 1,3-bis(diphenylphosphino)propane, dppb = 1,4-bis(diphenylphosphino)butane, dpppn = 1,5-bis(diphenylphosphino)pentane) of the [Ni(P,P)(dithiol)] type have been synthesized. The compounds have been characterized by elemental analysis, IR and electronic spectroscopies, magnetochemical, conductivity measurements and thermal analysis. Single crystal X-ray analysis of [Ni(dpppn)(mnt)] confirmed a planar geometry of NiP2S2 chromophore. Possible practical applications such as use of these compounds for vulcanization accelerators and their anticholinesterase activity were evaluated. (en)
Title	Planar Ni(II) 1,2-dithiolenes involving bidentate P-donor ligands Planar Ni(II) 1,2-dithiolenes involving bidentate P-donor ligands (en)
skos:prefLabel	Planar Ni(II) 1,2-dithiolenes involving bidentate P-donor ligands Planar Ni(II) 1,2-dithiolenes involving bidentate P-donor ligands (en)
skos:notation	RIV/60162694:G44__/09:00002172!RIV10-MO0-G44_____
http://linked.open...avai/riv/aktivita	S Z
http://linked.open...avai/riv/aktivity	S, Z(MO0FVZ0000604)
http://linked.open...iv/cisloPeriodika	16
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Kuča, Kamil Pohanka, Doc. RNDr. PhD, Miroslav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ministerstvo obrany / Univerzita obrany - Fakulta vojenského zdravotnictví Hradec Králové
http://linked.open...dnocenehoVysledku	333557
http://linked.open...ai/riv/idVysledku	RIV/60162694:G44__/09:00002172
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	nickel(II); dithiolenes; X-ray structure; vulcanization agents; cholinesterase; inhibitor (en)
http://linked.open.../riv/klicoveSlovo	cholinesterase dithiolenes vulcanization agents X-ray structure inhibitor nickel(II)
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[EFC8DC03B37D]
http://linked.open...i/riv/nazevZdroje	Polyhedron
http://linked.open...in/vavai/riv/obor	FP
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	28
http://linked.open...iv/tvurceVysledku	Kuča, Kamil Pohanka, Miroslav Herich, P. Kamenicek, J. Olsovsky, M.
http://linked.open...ain/vavai/riv/wos	000271781200023
http://linked.open...n/vavai/riv/zamer	Informační zabezpečení krizového managementu pro oblast zdravotnictví
issn	0277-5387
number of pages	5 (xsd:int)
http://localhost/t...ganizacniJednotka	G44
is http://linked.open...avai/riv/vysledek of	Planar Ni(II) 1,2-dithiolenes involving bidentate P-donor ligands

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