About: Comparative study of nucleophilic efficacy of pralidoxime towards phosphorus, sulphur and thiophosphorus based esters     Goto   Sponge   NotDistinct   Permalink

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  • Nucleophilic substitution reaction of p-nitrophenyldiphenyl phosphate, p-nitrophenyl p- toluene sulfonate and insecticide fenitrothion with pralidoxime have been studied at 27oC in the presence of different cationic surfactants. Micellar rate enhancements increase as the cationic head group is made less polar. The order of cleavage of different electrophilic centre by pralidoxime is P=O > S=O > P=S.
  • Nucleophilic substitution reaction of p-nitrophenyldiphenyl phosphate, p-nitrophenyl p- toluene sulfonate and insecticide fenitrothion with pralidoxime have been studied at 27oC in the presence of different cationic surfactants. Micellar rate enhancements increase as the cationic head group is made less polar. The order of cleavage of different electrophilic centre by pralidoxime is P=O > S=O > P=S. (en)
Title
  • Comparative study of nucleophilic efficacy of pralidoxime towards phosphorus, sulphur and thiophosphorus based esters
  • Comparative study of nucleophilic efficacy of pralidoxime towards phosphorus, sulphur and thiophosphorus based esters (en)
skos:prefLabel
  • Comparative study of nucleophilic efficacy of pralidoxime towards phosphorus, sulphur and thiophosphorus based esters
  • Comparative study of nucleophilic efficacy of pralidoxime towards phosphorus, sulphur and thiophosphorus based esters (en)
skos:notation
  • RIV/60162694:G44__/09:00002171!RIV10-MO0-G44_____
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  • P(OVUOFVZ200803)
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  • 1
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  • 307650
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  • RIV/60162694:G44__/09:00002171
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  • pralidoxime; cationic surfactants; kinetics; phosphate ester (en)
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  • HU - Maďarsko
http://linked.open...ontrolniKodProRIV
  • [00EC4CDB89BA]
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  • Reaction Kinetics and Catalysis Letters
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  • 98
http://linked.open...iv/tvurceVysledku
  • Kuča, Kamil
  • Marek, Jan
  • Ghosh, Kallol K
  • Tiwari, Shuch
http://linked.open...ain/vavai/riv/wos
  • 000270190100012
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  • 0133-1736
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  • G44
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