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  • Pulsed IR laser ablation of ferrous sulfide (FeS) in a vacuum has been studied using scanning and transmission electron microscopy and X-ray diffraction. This allows the analysis of the surface morphology and composition of the irradiated target and also of the coats deposited on unheated Ta, silica and Cu substrates. It is observed that a noncongruent ablation of FeS results in the deposition of nanosized FeS-containing FeS1_x amorphous coats on the silica and tantalum, and in the deposition of crystalline copper sulfide-containing amorphous Cu2S phases on copper. The detected amorphous Cu2S phase, crystalline and nanocrystalline chalcocite Cu2S, bornite Cu5FeS4, digenite Cu9S5 and blaubleibend covellite are formed through the reactive deposition of FeS1_x particles on the topmost Cu layers. This finding is the first example of the reactive deposition of laser ablated inorganic compounds on unheated surfaces and may spur more interest in using this simple process with various inorganic compounds to achieve reactive modifications of other materials.
  • Pulsed IR laser ablation of ferrous sulfide (FeS) in a vacuum has been studied using scanning and transmission electron microscopy and X-ray diffraction. This allows the analysis of the surface morphology and composition of the irradiated target and also of the coats deposited on unheated Ta, silica and Cu substrates. It is observed that a noncongruent ablation of FeS results in the deposition of nanosized FeS-containing FeS1_x amorphous coats on the silica and tantalum, and in the deposition of crystalline copper sulfide-containing amorphous Cu2S phases on copper. The detected amorphous Cu2S phase, crystalline and nanocrystalline chalcocite Cu2S, bornite Cu5FeS4, digenite Cu9S5 and blaubleibend covellite are formed through the reactive deposition of FeS1_x particles on the topmost Cu layers. This finding is the first example of the reactive deposition of laser ablated inorganic compounds on unheated surfaces and may spur more interest in using this simple process with various inorganic compounds to achieve reactive modifications of other materials. (en)
Title
  • Reactive deposition of laser ablated FeS1_x particles on a copper surface
  • Reactive deposition of laser ablated FeS1_x particles on a copper surface (en)
skos:prefLabel
  • Reactive deposition of laser ablated FeS1_x particles on a copper surface
  • Reactive deposition of laser ablated FeS1_x particles on a copper surface (en)
skos:notation
  • RIV/49777513:23640/14:43921829!RIV15-MSM-23640___
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  • P(ED2.1.00/03.0088)
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  • 23
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  • RIV/49777513:23640/14:43921829
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  • inorganic compound; reactive deposition; ablation; Pulsed laser deposition (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [966F3EA7B7FD]
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  • 4
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  • Bezdička, Petr
  • Kupčík, Jaroslav
  • Pokorná, Dana
  • Pola, Josef
  • Urbanová, Markéta
  • Křenek, Tomáš
issn
  • 2046-2069
number of pages
http://bibframe.org/vocab/doi
  • 10.1039/c3ra46580b
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  • 23640
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