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  • Modeling tradition is reviewed within its historical maturity from Plato (hexagonal) do Penrose (pentagonal symmetry). Metaphors in nonisothermal kinetics achieved a wide application mostly employing models derived by means of undemanding isothermal descriptions. Geometrical basis of such modeling is revised and discussed in terms of symmetrical and asymmetrical (pentagonal) schemes. The properties of interface (reaction separating line) are found decisive in all cases of heterogeneous kinetics. Application of fractal geometry is accredited and associated formal kinetic models based on nonintegral power exponents are acknowledged. Typical erroneous beliefs are dealt with showing common kinetic misinterpretation of measured data and associated mathematical manipulability of kinetic equations. The correction of a measured DTA peak is mentioned assuming the effects of heat inertia and temperature gradients. Itemized 115 citations with titles.
  • Modeling tradition is reviewed within its historical maturity from Plato (hexagonal) do Penrose (pentagonal symmetry). Metaphors in nonisothermal kinetics achieved a wide application mostly employing models derived by means of undemanding isothermal descriptions. Geometrical basis of such modeling is revised and discussed in terms of symmetrical and asymmetrical (pentagonal) schemes. The properties of interface (reaction separating line) are found decisive in all cases of heterogeneous kinetics. Application of fractal geometry is accredited and associated formal kinetic models based on nonintegral power exponents are acknowledged. Typical erroneous beliefs are dealt with showing common kinetic misinterpretation of measured data and associated mathematical manipulability of kinetic equations. The correction of a measured DTA peak is mentioned assuming the effects of heat inertia and temperature gradients. Itemized 115 citations with titles. (en)
Title
  • Rationale and Fallacy of Thermoanalytical Kinetic patterns: how we model subject matter
  • Rationale and Fallacy of Thermoanalytical Kinetic patterns: how we model subject matter (en)
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  • Rationale and Fallacy of Thermoanalytical Kinetic patterns: how we model subject matter
  • Rationale and Fallacy of Thermoanalytical Kinetic patterns: how we model subject matter (en)
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  • RIV/49777513:23640/12:43916436!RIV13-MSM-23640___
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  • P(ED2.1.00/03.0088)
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  • 1
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  • 164151
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  • RIV/49777513:23640/12:43916436
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  • DTA; misinterpretation; evaluation; fractals; geometrical modeling; reaction in solid state, reaction mechanism; nonisothermal kinetics (en)
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  • DE - Spolková republika Německo
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  • [C9D5329E38FF]
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  • Journal of thermal analysis and calorimetry
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  • 110
http://linked.open...iv/tvurceVysledku
  • Šesták, Jaroslav
http://linked.open...ain/vavai/riv/wos
  • 000309709900002
issn
  • 1388-6150
number of pages
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  • 10.1007/s10973-011-2089-1
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  • 23640
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