About: Complexation of valinomycin with some univalent organic cations in nitrobenzene saturated with water     Goto   Sponge   NotDistinct   Permalink

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  • From extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium C+(aq) + 1.Cs+(nb) double left right arrow 1.C+(nb)+Cs+(aq) taking place in the two-phase water-nitrobenzene system (C+ = methylammonium, ethylammonium, propylammonium, ethanolammonium, diethanolammonium, triethanolammonium, protonated tyramine, protonated dopamine, or protonated DL-noradrenaline; 1 = valinomycin; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the 1.C+ complex species in nitrobenzene saturated with water were calculated; they were found to increase in the following cation order: propylammonium<ethylammonium<protonated tyramine<methylammonium<protonated dopamine<triethanolammonium<diethanolammonium<ethanolammonium<protonated DL-noradrenaline.
  • From extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium C+(aq) + 1.Cs+(nb) double left right arrow 1.C+(nb)+Cs+(aq) taking place in the two-phase water-nitrobenzene system (C+ = methylammonium, ethylammonium, propylammonium, ethanolammonium, diethanolammonium, triethanolammonium, protonated tyramine, protonated dopamine, or protonated DL-noradrenaline; 1 = valinomycin; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the 1.C+ complex species in nitrobenzene saturated with water were calculated; they were found to increase in the following cation order: propylammonium<ethylammonium<protonated tyramine<methylammonium<protonated dopamine<triethanolammonium<diethanolammonium<ethanolammonium<protonated DL-noradrenaline. (en)
Title
  • Complexation of valinomycin with some univalent organic cations in nitrobenzene saturated with water
  • Complexation of valinomycin with some univalent organic cations in nitrobenzene saturated with water (en)
skos:prefLabel
  • Complexation of valinomycin with some univalent organic cations in nitrobenzene saturated with water
  • Complexation of valinomycin with some univalent organic cations in nitrobenzene saturated with water (en)
skos:notation
  • RIV/46356088:_____/13:#0001432!RIV14-MPO-46356088
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • N
http://linked.open...iv/cisloPeriodika
  • January
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 66479
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  • RIV/46356088:_____/13:#0001432
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  • Univalent organic cations; Valinomycin; Complexation; Extraction and stability constants; Water-nitrobenzene system (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [293B26A44CAD]
http://linked.open...i/riv/nazevZdroje
  • Journal of Mollecular Liquids
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 177
http://linked.open...iv/tvurceVysledku
  • Selucký, Pavel
http://linked.open...ain/vavai/riv/wos
  • 000313759700062
issn
  • 0167-7322
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.molliq.2012.10.028
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