About: Uranium recovery from LiF-CaF2-UF4-GdF3 system on Ni electrode     Goto   Sponge   NotDistinct   Permalink

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  • Electrochemistry of gadolinium and uranium in LiF-CaF2 (79-21 mol%) melt was studied using reactive Ni electrode and alloying reactions were observed. Deposits of gadolinium and uranium in the form of Gd-Ni and U-Ni intermetallic alloys were obtained after electrolysis by modulated current. Electrolysis of the same parameters was used also in the complex system of LiF-CaF2-UF4-GdF3 to demonstrate feasibility of selective deposition of uranium and therefore its separation from the system. Compact deposit of U-Ni alloy containing only traces of gadolinium was obtained.
  • Electrochemistry of gadolinium and uranium in LiF-CaF2 (79-21 mol%) melt was studied using reactive Ni electrode and alloying reactions were observed. Deposits of gadolinium and uranium in the form of Gd-Ni and U-Ni intermetallic alloys were obtained after electrolysis by modulated current. Electrolysis of the same parameters was used also in the complex system of LiF-CaF2-UF4-GdF3 to demonstrate feasibility of selective deposition of uranium and therefore its separation from the system. Compact deposit of U-Ni alloy containing only traces of gadolinium was obtained. (en)
Title
  • Uranium recovery from LiF-CaF2-UF4-GdF3 system on Ni electrode
  • Uranium recovery from LiF-CaF2-UF4-GdF3 system on Ni electrode (en)
skos:prefLabel
  • Uranium recovery from LiF-CaF2-UF4-GdF3 system on Ni electrode
  • Uranium recovery from LiF-CaF2-UF4-GdF3 system on Ni electrode (en)
skos:notation
  • RIV/46356088:_____/13:#0001362!RIV14-MPO-46356088
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • V
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 112819
http://linked.open...ai/riv/idVysledku
  • RIV/46356088:_____/13:#0001362
http://linked.open...riv/jazykVysledku
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  • Molten salt; Electrolysis; Spent nuclear fuel reprocessing; Pyrochemical reprocessing; Uranium; Gadolinium (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [2599D66CC529]
http://linked.open...i/riv/nazevZdroje
  • Journal of Radioanalytical and Nuclear Chemistry
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  • 298
http://linked.open...iv/tvurceVysledku
  • Straka, Martin
  • Szatmáry, Lórant
  • Mareček, Martin
  • Korenko, Michal
http://linked.open...ain/vavai/riv/wos
  • 000324546100049
issn
  • 0236-5731
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s10967-013-2436-8
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