About: Complexation of some univalent organic cations with benzo-18-crown-6 in nitrobenzene saturated with water     Goto   Sponge   NotDistinct   Permalink

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  • rom extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium C+(aq) + 1 center dot Na+(nb) <=> 1 center dot C+ (nb) + Na+(aq) taking place in the two-phase water-nitrobenzene system (C+ = methylammonium, ethylammonium, propylammonium, ethanolammonium, diethanolammonium, triethanolammonium, cation TRIS+, hydrazinium, hydroxylammonium; 1 = benzo-18-crown-6; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the 1 center dot C+ cationic complex species in nitrobenzene saturated with water were calculated; they were found to increase in the following cation order: triethanolammonium < propylammonium < ethylammonium, diethanolammonium < methylammonium < ethanolammonium < cation TRIS+ < hydrazinium < hydroxylammonium.
  • rom extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium C+(aq) + 1 center dot Na+(nb) <=> 1 center dot C+ (nb) + Na+(aq) taking place in the two-phase water-nitrobenzene system (C+ = methylammonium, ethylammonium, propylammonium, ethanolammonium, diethanolammonium, triethanolammonium, cation TRIS+, hydrazinium, hydroxylammonium; 1 = benzo-18-crown-6; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the 1 center dot C+ cationic complex species in nitrobenzene saturated with water were calculated; they were found to increase in the following cation order: triethanolammonium < propylammonium < ethylammonium, diethanolammonium < methylammonium < ethanolammonium < cation TRIS+ < hydrazinium < hydroxylammonium. (en)
Title
  • Complexation of some univalent organic cations with benzo-18-crown-6 in nitrobenzene saturated with water
  • Complexation of some univalent organic cations with benzo-18-crown-6 in nitrobenzene saturated with water (en)
skos:prefLabel
  • Complexation of some univalent organic cations with benzo-18-crown-6 in nitrobenzene saturated with water
  • Complexation of some univalent organic cations with benzo-18-crown-6 in nitrobenzene saturated with water (en)
skos:notation
  • RIV/46356088:_____/12:#0001245!RIV13-MPO-46356088
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  • N, S
http://linked.open...iv/cisloPeriodika
  • 5
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 128200
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  • RIV/46356088:_____/12:#0001245
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  • Univalent organic cations; Benzo-18-crown-6; Complexation; Extraction and stability constants; Water - nitrobenzene system (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • PL - Polská republika
http://linked.open...ontrolniKodProRIV
  • [2B51F4FC7F87]
http://linked.open...i/riv/nazevZdroje
  • Central European Journal of Chemistry
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  • 10
http://linked.open...iv/tvurceVysledku
  • Selucký, Pavel
http://linked.open...ain/vavai/riv/wos
  • 000306695700011
issn
  • 1895-1066
number of pages
http://bibframe.org/vocab/doi
  • 10.2478/s11532-012-0052-z
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