About: Determination of Cs-137 and Sr-85 transport parameters in fucoidic sand columns and groundwater system     Goto   Sponge   NotDistinct   Permalink

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  • The determination is based on the evaluation of experimentally obtained breakthrough curves using the erfc-function. The first method is founded on the assumption of a reversible linear sorption/desorption isotherm of radionuclides on solid phase with constant distribution and retardation coefficients, whereas the second one is based on the assumption of a reversible non-linear sorption/desorption isotherm described with the Freundlich equation, i.e., with non-constant distribution and retardation coefficients. Undisturbed cores of 5 cm in diameter and 10 cm long were embedded in the Eprosin-type cured epoxide resin column. In this study the so-called Cenomanian background groundwater was used as transport medium. The groundwater containing radionuclides was introduced at the bottom of the columns at about 4 mL h(-1) constant flow-rate. The results have shown that in the investigated fucoidic sands: (i) the sorption was in principle characterized by linear isotherms and the corresponding retardation coefficients of Cs-137 and Sr-85, depending on the type of sample, were approximately 13 or 44 and 5 or 15, respectively; (ii) the desorption was characterized by non-linear isotherms, and the retardation coefficients of the same radionuclides ranged between 23-50 and 5-25, respectively. The values of the hydrodynamic dispersion coefficients of these radionuclides varied between 0.43-1.2 cm(2) h(-1).
  • The determination is based on the evaluation of experimentally obtained breakthrough curves using the erfc-function. The first method is founded on the assumption of a reversible linear sorption/desorption isotherm of radionuclides on solid phase with constant distribution and retardation coefficients, whereas the second one is based on the assumption of a reversible non-linear sorption/desorption isotherm described with the Freundlich equation, i.e., with non-constant distribution and retardation coefficients. Undisturbed cores of 5 cm in diameter and 10 cm long were embedded in the Eprosin-type cured epoxide resin column. In this study the so-called Cenomanian background groundwater was used as transport medium. The groundwater containing radionuclides was introduced at the bottom of the columns at about 4 mL h(-1) constant flow-rate. The results have shown that in the investigated fucoidic sands: (i) the sorption was in principle characterized by linear isotherms and the corresponding retardation coefficients of Cs-137 and Sr-85, depending on the type of sample, were approximately 13 or 44 and 5 or 15, respectively; (ii) the desorption was characterized by non-linear isotherms, and the retardation coefficients of the same radionuclides ranged between 23-50 and 5-25, respectively. The values of the hydrodynamic dispersion coefficients of these radionuclides varied between 0.43-1.2 cm(2) h(-1). (en)
Title
  • Determination of Cs-137 and Sr-85 transport parameters in fucoidic sand columns and groundwater system
  • Determination of Cs-137 and Sr-85 transport parameters in fucoidic sand columns and groundwater system (en)
skos:prefLabel
  • Determination of Cs-137 and Sr-85 transport parameters in fucoidic sand columns and groundwater system
  • Determination of Cs-137 and Sr-85 transport parameters in fucoidic sand columns and groundwater system (en)
skos:notation
  • RIV/46356088:_____/11:#0001159!RIV12-MPO-46356088
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • P(FT-TA3/070), Z(MSM6840770020)
http://linked.open...iv/cisloPeriodika
  • 5
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 193817
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  • RIV/46356088:_____/11:#0001159
http://linked.open...riv/jazykVysledku
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  • Sorption and desorption; Linear and non-linear isotherms; Dynamic flow; Breakthrough curves (en)
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  • PL - Polská republika
http://linked.open...ontrolniKodProRIV
  • [1571C9B88E2D]
http://linked.open...i/riv/nazevZdroje
  • Central European Journal of Chemistry
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http://linked.open...v/svazekPeriodika
  • 9
http://linked.open...iv/tvurceVysledku
  • Palágyi, Štefan
http://linked.open...ain/vavai/riv/wos
  • 000293020400005
http://linked.open...n/vavai/riv/zamer
issn
  • 1895-1066
number of pages
http://bibframe.org/vocab/doi
  • 10.2478/s11532-011-0076-9
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