About: Semi-pilot scale environment friendly photocatalytic degradation of 4-chlorophenol with singlet oxygen species-Direct comparison with H2O2/UV-C reaction system

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About: Semi-pilot scale environment friendly photocatalytic degradation of 4-chlorophenol with singlet oxygen species-Direct comparison with H2O2/UV-C reaction system Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Metal phthalocyanines in the presence of visible light are applied in the semi-pilot level for the degradation of organic pollution represented by 4-chlorophenol (4-CP) with potential further scale-up. The effectiveness of the process based on the generation of singlet oxygen active species is compared with commonly used method of photochemical oxidation with hydrogen peroxide in the presence of ultraviolet irradiation. The direct comparison of the reaction systems was conceivable because both oxidation processes were carried out in identical experimental arrangements and under identical reaction conditions. The comparison was performed in terms of 4-CP conversion, TOC removal, apparent quantum yields, kinetic constants, and economy considerations. It must be emphasized there have been no reports on the semi pilot scale utilization of phthalocyanines for decontamination purposes previously. Metal phthalocyanines in the presence of visible light are applied in the semi-pilot level for the degradation of organic pollution represented by 4-chlorophenol (4-CP) with potential further scale-up. The effectiveness of the process based on the generation of singlet oxygen active species is compared with commonly used method of photochemical oxidation with hydrogen peroxide in the presence of ultraviolet irradiation. The direct comparison of the reaction systems was conceivable because both oxidation processes were carried out in identical experimental arrangements and under identical reaction conditions. The comparison was performed in terms of 4-CP conversion, TOC removal, apparent quantum yields, kinetic constants, and economy considerations. It must be emphasized there have been no reports on the semi pilot scale utilization of phthalocyanines for decontamination purposes previously. (en)
Title	Semi-pilot scale environment friendly photocatalytic degradation of 4-chlorophenol with singlet oxygen species-Direct comparison with H2O2/UV-C reaction system Semi-pilot scale environment friendly photocatalytic degradation of 4-chlorophenol with singlet oxygen species-Direct comparison with H2O2/UV-C reaction system (en)
skos:prefLabel	Semi-pilot scale environment friendly photocatalytic degradation of 4-chlorophenol with singlet oxygen species-Direct comparison with H2O2/UV-C reaction system Semi-pilot scale environment friendly photocatalytic degradation of 4-chlorophenol with singlet oxygen species-Direct comparison with H2O2/UV-C reaction system (en)
skos:notation	RIV/44555601:13520/14:43885953!RIV15-MSM-13520___
http://linked.open...avai/riv/aktivita	I P S
http://linked.open...avai/riv/aktivity	I, P(TA03010548), S
http://linked.open...iv/cisloPeriodika	160
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Bůžek, Daniel Klusoň, Petr Hejda, Stanislav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Jana Evangelisty Purkyně v Ústí nad Labem / Fakulta životního prostředí
http://linked.open...dnocenehoVysledku	44430
http://linked.open...ai/riv/idVysledku	RIV/44555601:13520/14:43885953
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Water treatment; UV-C/H2O2; Hydrogen peroxide; Singlet oxygen; Photochemical oxidation; Photocatalysis; Phthalocyanine (en)
http://linked.open.../riv/klicoveSlovo	Photocatalysis Photochemical oxidation UV-C/H2O2 Water treatment Singlet oxygen Phthalocyanine Hydrogen peroxide
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[EF5ABCAB7DE8]
http://linked.open...i/riv/nazevZdroje	Applied Catalysis B-Environmental
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Research and development of advanced thin film sensors for direct monitoring of the time variable by means of preciously calibrated colour change
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	2014
http://linked.open...iv/tvurceVysledku	Hejda, Stanislav Klusoň, Petr Mašín, Pavel Krystyník, Pavel Bůžek, Daniel Tito, Duarte Novaes
http://linked.open...ain/vavai/riv/wos	000340687900054
issn	0926-3373
number of pages	8 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.apcatb.2014.05.051
http://localhost/t...ganizacniJednotka	13520

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