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Description
  • Byl zpracován přehled metod pro stanovení rovnovážných konstant pro vedlejší rovnováhy uplatňující se při separacích metodami kapalinové chromatografie a kapilární elektroforézy. Jedná se zejména o acidobazické, komplexotvorné rovnováhy, iontově asociační a iontově párové rovnováhy. Byly odvozeny matematické vztahy mezi retenčními nebo migračními charakteristikami a složením pracovních roztoků. Bylo popsáno experimentální uspořádání pro měření rovnovážných konstant. (cs)
  • Methods of determination of equilibrium constants were rewieved for the side equilibria taking place in liquid chromatographic and electrophoretic separations, namely for acid-base, complex-forming, ion assiciation and other equilibria. Mathematical relationships between the retention or migration characteristics and the composition of working solutions were derived, and the respective experimental arrangements were described.
  • Methods of determination of equilibrium constants were rewieved for the side equilibria taking place in liquid chromatographic and electrophoretic separations, namely for acid-base, complex-forming, ion assiciation and other equilibria. Mathematical relationships between the retention or migration characteristics and the composition of working solutions were derived, and the respective experimental arrangements were described. (en)
Title
  • Stanovení rovnovážných konstant z chromatografických a elektroforetických měření (cs)
  • Determination of equilibrium constants from chromatographic and electrophoretic measurements
  • Determination of equilibrium constants from chromatographic and electrophoretic measurements (en)
skos:prefLabel
  • Stanovení rovnovážných konstant z chromatografických a elektroforetických měření (cs)
  • Determination of equilibrium constants from chromatographic and electrophoretic measurements
  • Determination of equilibrium constants from chromatographic and electrophoretic measurements (en)
skos:notation
  • RIV/44555601:13520/04:00002493!RIV/2005/MSM/135205/N
http://linked.open.../vavai/riv/strany
  • 15-28
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM 135200001)
http://linked.open...iv/cisloPeriodika
  • 1-2
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 560069
http://linked.open...ai/riv/idVysledku
  • RIV/44555601:13520/04:00002493
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • chemical equilibria;chromatography;electrophoresis (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [B51C4460CDFB]
http://linked.open...i/riv/nazevZdroje
  • Journal of Chromatography A
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 1037
http://linked.open...iv/tvurceVysledku
  • Janoš, Pavel
http://linked.open...n/vavai/riv/zamer
issn
  • 0021-9673
number of pages
http://localhost/t...ganizacniJednotka
  • 13520
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