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Description
| - An improved two-dimensional (2D) equation of state is proposed on the basis of an expression from the scaled particle theory. For pure hard disks, the virial coefficients B3 - B15 are determined and compared with their pseudo-experimental values. The 2D compressibility factor, Z, of pure hard disks is evaluated from the improved equation of state (IEOS) and compared with Z from Henderson's relation and with simulation data. Similarly, Z of mixtures of hard disks with the diameter ratios sigma2/sigma1 =1,2,3,4,5 and 10 and mole fractions x1=0.5 and 0.25 were compared with the corresponding simulation data. A fair agreement was found in the case of pure fluid as well as the studied mixtures.Third and fourth virial coefficients of three types of convex figures - hard ellipses, hard spherocylinders and rectangles - were determined from IEOS and a fair agreement with pseudo-experiment was found. Next, the predictive capability of the considered IEOS was investigated for 2D hard prolatesphero-cylinder and systems of hard ellipses with three values of the aspect ratio, k=a/b, k= 2, 4 and 6 (where a,b denote semi-axes of an ellipse). The compressibility factor of the 2D-spherocylinders compared well with the MC data, in the case of hard ellipses, and the description is fair for the isotropic phase. DOI: 10.1080/00268976.2011.573508
- An improved two-dimensional (2D) equation of state is proposed on the basis of an expression from the scaled particle theory. For pure hard disks, the virial coefficients B3 - B15 are determined and compared with their pseudo-experimental values. The 2D compressibility factor, Z, of pure hard disks is evaluated from the improved equation of state (IEOS) and compared with Z from Henderson's relation and with simulation data. Similarly, Z of mixtures of hard disks with the diameter ratios sigma2/sigma1 =1,2,3,4,5 and 10 and mole fractions x1=0.5 and 0.25 were compared with the corresponding simulation data. A fair agreement was found in the case of pure fluid as well as the studied mixtures.Third and fourth virial coefficients of three types of convex figures - hard ellipses, hard spherocylinders and rectangles - were determined from IEOS and a fair agreement with pseudo-experiment was found. Next, the predictive capability of the considered IEOS was investigated for 2D hard prolatesphero-cylinder and systems of hard ellipses with three values of the aspect ratio, k=a/b, k= 2, 4 and 6 (where a,b denote semi-axes of an ellipse). The compressibility factor of the 2D-spherocylinders compared well with the MC data, in the case of hard ellipses, and the description is fair for the isotropic phase. DOI: 10.1080/00268976.2011.573508 (en)
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Title
| - Equation of state of hard disk and 2D convex bodies
- Equation of state of hard disk and 2D convex bodies (en)
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skos:prefLabel
| - Equation of state of hard disk and 2D convex bodies
- Equation of state of hard disk and 2D convex bodies (en)
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skos:notation
| - RIV/44555601:13440/11:43878463!RIV12-AV0-13440___
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http://linked.open...avai/predkladatel
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/44555601:13440/11:43878463
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Helmholtz energy; Compressibility factor; Surface density; Non-circular parameter; Virial coefficient; 2D hard spherocylinder; Ellipse; Disk; Equation of state (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1080/00268976.2011.573508
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http://localhost/t...ganizacniJednotka
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is http://linked.open...avai/riv/vysledek
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