About: Determination of electrochemical corrosion potential along the JMTR in-pile loop-II: Validation of ECP electrodes and the extrapolation of measured ECP data     Goto   Sponge   NotDistinct   Permalink

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  • In-pile loop experiments are one of the key technologies that can provide an understanding of corrosion behaviors of structural materials in nuclear power plants (NPPs). The experiments should be supported not only by reliable measurement tools to confirm corrosive conditions under neutron and gamma-ray irradiations but also by theoretical models for extrapolating the measured data to predict corrosion behaviors in NPPs.The relationships among electrochemical corrosion potential (ECP), metal surface conditions, exposure time, and other environmental conditions have been determined from in situ measurements of corrosion behaviors of stainless steel specimens exposed to H2O2 and O-2 in high-temperature water. Based on the relationships, a model to evaluate the ECP of stainless steel was developed by coupling an electrochemical model and a double-oxide layer model.Major conclusions obtained from the evaluation model are as follows: (a) The difference in ECP behaviors of the specimens exposed to H2O2 and O-2 were mainly from the thickness and developing rate of the inner oxide layers. (b) Calculated ECP behaviors, e.g., the different responses to H2O2 and O-2 and hysteresis and memory effects, agreed with the measured ones. (c) Neutron exposure might decrease ECP due to radiation-induced diffusion in the oxide layer.The ECP evaluation model will be applied to evaluation of corrosive conditions in the JMTR in-pile loop.
  • In-pile loop experiments are one of the key technologies that can provide an understanding of corrosion behaviors of structural materials in nuclear power plants (NPPs). The experiments should be supported not only by reliable measurement tools to confirm corrosive conditions under neutron and gamma-ray irradiations but also by theoretical models for extrapolating the measured data to predict corrosion behaviors in NPPs.The relationships among electrochemical corrosion potential (ECP), metal surface conditions, exposure time, and other environmental conditions have been determined from in situ measurements of corrosion behaviors of stainless steel specimens exposed to H2O2 and O-2 in high-temperature water. Based on the relationships, a model to evaluate the ECP of stainless steel was developed by coupling an electrochemical model and a double-oxide layer model.Major conclusions obtained from the evaluation model are as follows: (a) The difference in ECP behaviors of the specimens exposed to H2O2 and O-2 were mainly from the thickness and developing rate of the inner oxide layers. (b) Calculated ECP behaviors, e.g., the different responses to H2O2 and O-2 and hysteresis and memory effects, agreed with the measured ones. (c) Neutron exposure might decrease ECP due to radiation-induced diffusion in the oxide layer.The ECP evaluation model will be applied to evaluation of corrosive conditions in the JMTR in-pile loop. (en)
Title
  • Determination of electrochemical corrosion potential along the JMTR in-pile loop-II: Validation of ECP electrodes and the extrapolation of measured ECP data
  • Determination of electrochemical corrosion potential along the JMTR in-pile loop-II: Validation of ECP electrodes and the extrapolation of measured ECP data (en)
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  • Determination of electrochemical corrosion potential along the JMTR in-pile loop-II: Validation of ECP electrodes and the extrapolation of measured ECP data
  • Determination of electrochemical corrosion potential along the JMTR in-pile loop-II: Validation of ECP electrodes and the extrapolation of measured ECP data (en)
skos:notation
  • RIV/26722445:_____/13:#0000764!RIV14-MPO-26722445
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • N
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 68868
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  • RIV/26722445:_____/13:#0000764
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  • electrochemical corrosion potential; hydrogen peroxide; radiation-induced diffusion (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [55CB5998D38C]
http://linked.open...i/riv/nazevZdroje
  • Nuclear Technology
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 183
http://linked.open...iv/tvurceVysledku
  • Kysela, Jan
  • Kůs, Pavel
  • Všolák, Rudolf
http://linked.open...ain/vavai/riv/wos
  • 000321413600010
issn
  • 0029-5450
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