About: Influence of OH radicals on Organic Dyes in DC Diaphragm Discharge in Water Solutions     Goto   Sponge   NotDistinct   Permalink

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  • This contribution describes some selected processes occurring in the DC diaphragm discharge in liquids. Various chemical species are produced by such discharge type in water solutions. The main attention is focused on the creation of OH radicals and on the degradation of organic dyes dissolved in water by the discharge. Three azo-dyes of different conjugated system (colour) are compared. The dependence of both processes on the applied voltage (magnitude and polarity) and the used electrolyte is investiggated. The relation between OH radicals production and the dye decomposition by the discharge together with the possible reaction mechanism is discussed in the text. A possible influence of electrolysis is also taken into consideration.
  • This contribution describes some selected processes occurring in the DC diaphragm discharge in liquids. Various chemical species are produced by such discharge type in water solutions. The main attention is focused on the creation of OH radicals and on the degradation of organic dyes dissolved in water by the discharge. Three azo-dyes of different conjugated system (colour) are compared. The dependence of both processes on the applied voltage (magnitude and polarity) and the used electrolyte is investiggated. The relation between OH radicals production and the dye decomposition by the discharge together with the possible reaction mechanism is discussed in the text. A possible influence of electrolysis is also taken into consideration. (en)
  • Článek popisuje vybrané procesy ve stejnosměrném diafragmovém výboji v kapalinách. V takovémto výboji generovaném ve vodném roztoku vznikají různé chemicky reaktivní částice. Hlavní pozornost příspěvku je zaměřena na tvorbu OH radikálů a následnou destrukci organických barviv rozpuštěných ve vodě právě tímto výbojem. Porovnány jsou tři azobarviva s různým konjugovaným systémem (barvou). Zkoumána je závislost procesů ve výboji na napětí (velikosti a polaritě) a použitém elektrolytu. V textu je diskutovánn vztah mezi produkcí OH radikálů a rozkladem barviva výbojem, jakožto i možný reakční mechanismus. V úvahu je rovněž brán vliv elektrolýzy. (cs)
Title
  • Influence of OH radicals on Organic Dyes in DC Diaphragm Discharge in Water Solutions
  • Influence of OH radicals on Organic Dyes in DC Diaphragm Discharge in Water Solutions (en)
  • Vliv OH radikálů na rozklad organických látek v diafragmovém výboji ve vodných roztocích (cs)
skos:prefLabel
  • Influence of OH radicals on Organic Dyes in DC Diaphragm Discharge in Water Solutions
  • Influence of OH radicals on Organic Dyes in DC Diaphragm Discharge in Water Solutions (en)
  • Vliv OH radikálů na rozklad organických látek v diafragmovém výboji ve vodných roztocích (cs)
skos:notation
  • RIV/00216305:26310/05:PU50709!RIV06-GA0-26310___
http://linked.open.../vavai/riv/strany
  • 18-226
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  • P(GD202/03/H162)
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  • 524767
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  • RIV/00216305:26310/05:PU50709
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  • diaphragm discharge, discharge in liquids, hydrogen peroxide generation, organic dyes decomposition (en)
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  • [FB28601242E5]
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  • Eindhoven
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  • Eindhoven
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  • Proceedings of ICPIG XXVII
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  • Krčma, František
  • Stará, Zdenka
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number of pages
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  • Eindhoven University of Technology
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  • 90-386-2231-7
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  • 26310
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