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  • Rate constants of unimolecular dissociation of molecules SF6 , SF5 , SF4 , SF3 ,SF2 have been computed by means of Kassel integrals interpolating both the values of low pressure and high pressure limits. The collision theory has been used for determination of low pressure rate constants , high pressure rate constants have been calculated by statistical adiabatic channel model. We have used obtained values to the study of the influence of different values of reaction rate constants on the kinetic commposition of the SF6 system during the extinction process in the switching arc.
  • Rate constants of unimolecular dissociation of molecules SF6 , SF5 , SF4 , SF3 ,SF2 have been computed by means of Kassel integrals interpolating both the values of low pressure and high pressure limits. The collision theory has been used for determination of low pressure rate constants , high pressure rate constants have been calculated by statistical adiabatic channel model. We have used obtained values to the study of the influence of different values of reaction rate constants on the kinetic commposition of the SF6 system during the extinction process in the switching arc. (en)
  • Rychlostní konstanty monomolekulární disociace molekul SF6, SF5, SF4, SF3, SF2 byly počítány pomocí Kasselových integrálů interpolací hodnot nízkotlaké a vysokotlaké limity. Srážková teorie byla použita při výpočtu hodnot nízkotlakých rychlostních konstant, vysokotlaké rychlostní konstanty byly poočítány pomocí modelu statistických adiabatických kanálů. Vypočítané hodnoty byly použity na určení vlivu různých hodnot rychlostních konstant na kinetické složení systému SF6 během vypínacího procesu ve spínaccím oblouku. (cs)
Title
  • Monomolekulární reakce v chemické kinetice plazmatu oblouku v SF6 (cs)
  • Unimolecular Reactions in Chemical Kinetics of SF6-Arc Plasma
  • Unimolecular Reactions in Chemical Kinetics of SF6-Arc Plasma (en)
skos:prefLabel
  • Monomolekulární reakce v chemické kinetice plazmatu oblouku v SF6 (cs)
  • Unimolecular Reactions in Chemical Kinetics of SF6-Arc Plasma
  • Unimolecular Reactions in Chemical Kinetics of SF6-Arc Plasma (en)
skos:notation
  • RIV/00216305:26220/03:PU39105!RIV06-GA0-26220___
http://linked.open.../vavai/riv/strany
  • 12-17
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  • P(GA102/02/1414), Z(MSM 262200022)
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  • 632077
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  • RIV/00216305:26220/03:PU39105
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  • Rateconstants, unimolecular dissociation, kinetic composition, arc plasma (en)
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  • [EA2F96CC0DB1]
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  • Liptovsky Mikulas, hotel Jamajka
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  • Bratislava
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  • Proceedings of the XIVth Symposium on Application of Plasma Processes
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  • Bartlová, Milada
  • Coufal, Oldřich
  • Bartl, Josef
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number of pages
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  • Univerzita Komenského v Bratislave. Katedra fyziky plazmy & Fyzikálny ústav
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  • 80-8040-195-0
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  • 26220
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