About: Proposal of Mercury Isolation Procedure Using Cold Vapor Method in Combination with Voltammetric Determination Using Totating Gold Electrode     Goto   Sponge   NotDistinct   Permalink

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Description
  • Byl navržen optimální postup úpravy a aktivace povrchu zlaté rotující diskové elektrody (AuRDE) před voltametrickým stanovením rtuti. Postup se skládá z leštění povrchu, elektrochemického cyklování a aktivace. Detekční limit pro přímé stanovení rtuti dosažený s takto připravenou elektrodou byl 8.26?10-10 mol L-1 (při zařazení 200 s akumulace). Dále byla vyvinuta metoda kvantitativní isolace rtuti ze složité matrice vzorku. V případě isolace rtuti z 1 litru vody byl stanoven detekční limit 6.23?10-11 mol L-1 (při analýze většího objemu je možné stanovit i mnohem nižší koncentrace rtuti). (cs)
  • The optimal process of pre-treatment and activation of gold rotating disc electrode (AuRDE) before voltammetric determination of mercury was proposed. This treatment consists from polishing of the electrode surface, electrochemical cycling, and activation. The detection limit, achieved using this way prepared working electrode, amounted to 8.26?10-10 mol L-1 for direct mercury determination in water solution (applying 200 s running accumulation). The procedure of the quantitative mercury isolation from complicated sample matrix was developed as well. It provides better selectivity and significant increase of sensitivity of mercury determination. In case of mercury isolation from one liter of water detection limit was 6.23?10-11 mol L-1 (analyzing greater sample volume the determined concentration could be lower)
  • The optimal process of pre-treatment and activation of gold rotating disc electrode (AuRDE) before voltammetric determination of mercury was proposed. This treatment consists from polishing of the electrode surface, electrochemical cycling, and activation. The detection limit, achieved using this way prepared working electrode, amounted to 8.26?10-10 mol L-1 for direct mercury determination in water solution (applying 200 s running accumulation). The procedure of the quantitative mercury isolation from complicated sample matrix was developed as well. It provides better selectivity and significant increase of sensitivity of mercury determination. In case of mercury isolation from one liter of water detection limit was 6.23?10-11 mol L-1 (analyzing greater sample volume the determined concentration could be lower) (en)
Title
  • Proposal of Mercury Isolation Procedure Using Cold Vapor Method in Combination with Voltammetric Determination Using Totating Gold Electrode
  • Návrh metody pro isolaci rtuti s využitím metody studených par v kombinaci s voltametrickým stanovením s pomocí rotující zlaté diskové elektrody (cs)
  • Proposal of Mercury Isolation Procedure Using Cold Vapor Method in Combination with Voltammetric Determination Using Totating Gold Electrode (en)
skos:prefLabel
  • Proposal of Mercury Isolation Procedure Using Cold Vapor Method in Combination with Voltammetric Determination Using Totating Gold Electrode
  • Návrh metody pro isolaci rtuti s využitím metody studených par v kombinaci s voltametrickým stanovením s pomocí rotující zlaté diskové elektrody (cs)
  • Proposal of Mercury Isolation Procedure Using Cold Vapor Method in Combination with Voltammetric Determination Using Totating Gold Electrode (en)
skos:notation
  • RIV/00216275:25510/06:00003952!RIV08-MSM-25510___
http://linked.open.../vavai/riv/strany
  • 479-495
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM0021627502)
http://linked.open...iv/cisloPeriodika
  • 5
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 495613
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25510/06:00003952
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • mercury; gold rotating disc electrode (AuRDE); pre-treatment; cold vapor method; differential pulse anodic stripping voltammetry (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • PL - Polská republika
http://linked.open...ontrolniKodProRIV
  • [5DF10B7D8AB8]
http://linked.open...i/riv/nazevZdroje
  • Central European Journal of Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 2006
http://linked.open...iv/tvurceVysledku
  • Chýlková, Jaromíra
  • Šelešovská, Renáta
  • Machalíková, Jaroslava
http://linked.open...n/vavai/riv/zamer
issn
  • 1895-1066
number of pages
http://localhost/t...ganizacniJednotka
  • 25510
is http://linked.open...avai/riv/vysledek of
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