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rdf:type
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Description
| - The synthesis of the pentacarbonylchromium complex [{2,6-(Me2NCH2)(2)C6H3}(Cl) SnCr(CO)(5)] is reported. Starting with this compound, organotin(II) pentacarbonylchromium methoxide [{2,6-(Me2NCH2)(2)C6H3}(OMe)SnCr(CO)(5)] was prepared and used for the synthesis of dimeric N -} Sn intramolecularly coordinated organotin(II) pentacarbonylchromium hydroxide [{2,6-(Me2NCH2)(2)C6H3}Sn(mu-OH)Cr(CO)(5)](2) by easy hydrolytic protocol. In addition, acid-base-type reaction of this latter compound with HOTf provided unprecedented cyclization product [6-(Me2NCH2)-2,3-(C6H3CH2OSn)Cr-(CO)(5)](2). The cyclization process is accompanied by the formation of a new C-O covalent bond along with the elimination of Me2NH.
- The synthesis of the pentacarbonylchromium complex [{2,6-(Me2NCH2)(2)C6H3}(Cl) SnCr(CO)(5)] is reported. Starting with this compound, organotin(II) pentacarbonylchromium methoxide [{2,6-(Me2NCH2)(2)C6H3}(OMe)SnCr(CO)(5)] was prepared and used for the synthesis of dimeric N -} Sn intramolecularly coordinated organotin(II) pentacarbonylchromium hydroxide [{2,6-(Me2NCH2)(2)C6H3}Sn(mu-OH)Cr(CO)(5)](2) by easy hydrolytic protocol. In addition, acid-base-type reaction of this latter compound with HOTf provided unprecedented cyclization product [6-(Me2NCH2)-2,3-(C6H3CH2OSn)Cr-(CO)(5)](2). The cyclization process is accompanied by the formation of a new C-O covalent bond along with the elimination of Me2NH. (en)
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Title
| - Deamination of N -} Sn-Coordinated Organotin(II) Hydroxide: Formation of a New C-O Covalent Bond
- Deamination of N -} Sn-Coordinated Organotin(II) Hydroxide: Formation of a New C-O Covalent Bond (en)
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skos:prefLabel
| - Deamination of N -} Sn-Coordinated Organotin(II) Hydroxide: Formation of a New C-O Covalent Bond
- Deamination of N -} Sn-Coordinated Organotin(II) Hydroxide: Formation of a New C-O Covalent Bond (en)
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skos:notation
| - RIV/00216275:25310/14:39898824!RIV15-MSM-25310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/14:39898824
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Bond; Covalent; C-O; New; Formation; Hydroxide; OrganotinII; Sn-Coordinated; Deamination (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - DE - Spolková republika Německo
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - European Journal of Inorganic Chemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Dostál, Libor
- Jambor, Roman
- Růžička, Aleš
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
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http://localhost/t...ganizacniJednotka
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