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Description
| - The synthesis of the C,N-chelated homoleptic organotetrylenes (L1)2E (1, E = Sn; 2, E = Pb) and of the tungsten pentacarbonyl complex (L1)2SnW(CO)5 (3), containing the sterically demanding C,N-chelating ligand L1 (L1 = [2-{(C6H3-2,6-Pri2)N?CH}C6H4]?) is reported. In contrast, the use of the C,N-chelated ligand L2 (L2 = [2-{(C6H3-2,6-Pri2)N?C(Me)}C6H2(OCH2O)]?) provided either the homoleptic stannylene (L2)2Sn (4) or the C,N-chelated chlorostannylene (L2)SnCl (5). All attempts to convert the latter into the corresponding ditin compound [L2Sn]2 failed, however, and resulted in the isolation of 4 and elemental tin. These attempts also provided the unprecedented complex [2-{(C6H3-2,6-Pri2)N?C(Me)}C6H2(OCH2O)][2-{(C6H3-2,6-Pri2)NHCH(Me)}C6H2(OCH2O)]Sn (6).
- The synthesis of the C,N-chelated homoleptic organotetrylenes (L1)2E (1, E = Sn; 2, E = Pb) and of the tungsten pentacarbonyl complex (L1)2SnW(CO)5 (3), containing the sterically demanding C,N-chelating ligand L1 (L1 = [2-{(C6H3-2,6-Pri2)N?CH}C6H4]?) is reported. In contrast, the use of the C,N-chelated ligand L2 (L2 = [2-{(C6H3-2,6-Pri2)N?C(Me)}C6H2(OCH2O)]?) provided either the homoleptic stannylene (L2)2Sn (4) or the C,N-chelated chlorostannylene (L2)SnCl (5). All attempts to convert the latter into the corresponding ditin compound [L2Sn]2 failed, however, and resulted in the isolation of 4 and elemental tin. These attempts also provided the unprecedented complex [2-{(C6H3-2,6-Pri2)N?C(Me)}C6H2(OCH2O)][2-{(C6H3-2,6-Pri2)NHCH(Me)}C6H2(OCH2O)]Sn (6). (en)
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Title
| - Intramolecularly C,N-Coordinated Homo- and Heteroleptic Organostannylenes
- Intramolecularly C,N-Coordinated Homo- and Heteroleptic Organostannylenes (en)
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skos:prefLabel
| - Intramolecularly C,N-Coordinated Homo- and Heteroleptic Organostannylenes
- Intramolecularly C,N-Coordinated Homo- and Heteroleptic Organostannylenes (en)
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skos:notation
| - RIV/00216275:25310/14:39898823!RIV15-MSM-25310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/14:39898823
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Organostannylenes; Heteroleptic; and; Homo-; C,N-Coordinated; Intramolecularly (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Dostál, Libor
- Jambor, Roman
- Novák, Miroslav
- Růžička, Aleš
- Bouška, Marek
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
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http://localhost/t...ganizacniJednotka
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