About: Reduction of C,N-chelated chloroborane: straightforward formation of the unprecedented 1H-2,1-benzazaborolyl potassium salt

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Reduction of C,N-chelated chloroborane [2-(CH-NtBu)C6H4]BPhCl (1) with the potassium metal afforded (3,3')-bis(1-Ph-2-tBu-1H-2,1-benzazaborole) (2). Compound 2 is formed via C-C reductive coupling reaction. Subsequent reduction of 2 with two equivalents of the potassium metal produced orange crystals of 1Ph-2tBu-1H-2,1-benzazaborolyl (Bab) potassium salt K(THF)(Bab) (3). Compound 3 is able to react with simple electrophiles (MeI or Me3SiCl) resulting in the formation of substituted 1H-2,1-benzazaboroles. Reduction of C,N-chelated chloroborane [2-(CH-NtBu)C6H4]BPhCl (1) with the potassium metal afforded (3,3')-bis(1-Ph-2-tBu-1H-2,1-benzazaborole) (2). Compound 2 is formed via C-C reductive coupling reaction. Subsequent reduction of 2 with two equivalents of the potassium metal produced orange crystals of 1Ph-2tBu-1H-2,1-benzazaborolyl (Bab) potassium salt K(THF)(Bab) (3). Compound 3 is able to react with simple electrophiles (MeI or Me3SiCl) resulting in the formation of substituted 1H-2,1-benzazaboroles. (en)
Title	Reduction of C,N-chelated chloroborane: straightforward formation of the unprecedented 1H-2,1-benzazaborolyl potassium salt Reduction of C,N-chelated chloroborane: straightforward formation of the unprecedented 1H-2,1-benzazaborolyl potassium salt (en)
skos:prefLabel	Reduction of C,N-chelated chloroborane: straightforward formation of the unprecedented 1H-2,1-benzazaborolyl potassium salt Reduction of C,N-chelated chloroborane: straightforward formation of the unprecedented 1H-2,1-benzazaborolyl potassium salt (en)
skos:notation	RIV/00216275:25310/14:39898816!RIV15-MSM-25310___
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(GAP207/12/0223)
http://linked.open...iv/cisloPeriodika	24
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Hejda, Martin Dostál, Libor Růžička, Aleš Jambor, Roman
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	41716
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/14:39898816
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	analogs; derivatives; reactivity; lewis-acid; 2-azaborolyl complexes; 1; dihydroazaborolyl complexes; bond covalent radii (en)
http://linked.open.../riv/klicoveSlovo	analogs 1 derivatives reactivity 2-azaborolyl complexes lewis-acid bond covalent radii dihydroazaborolyl complexes
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[5FC15EA739C0]
http://linked.open...i/riv/nazevZdroje	Dalton Transactions
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Hybridní ligandy pro stabilizaci/specifickou aktivaci kovových center v nízkých oxidačních stavech.
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	43
http://linked.open...iv/tvurceVysledku	Dostál, Libor Jambor, Roman Růžička, Aleš Hejda, Martin Lyčka, Antonín
http://linked.open...ain/vavai/riv/wos	000336840900005
issn	1477-9226
number of pages	4 (xsd:int)
http://bibframe.org/vocab/doi	10.1039/c4dt00812j
http://localhost/t...ganizacniJednotka	25310

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