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Description
| - Five polymeric Mn(II) complexes with bridging carboxylato groups were prepared and structurally characterized. The bridging carboxylato ligand in double-chain coordination polymeric structures of [Mn(mu-3-NO(2)bz)(2) (bipy)](n)center dot nH(2)O, [Mn(mu-3,5-(NO2)(2)bz)(2)(bipy)](n), [Mn(mu-5-(NO2)sal)(2)(bipy)](n), and [Mn(mu-5-(NO2)sal)(2)(phen)](n), where 3-NO(2)bz(-) = 3-nitrobenzoate, 3,5-(NO2)(2)bz(-) = 3,5-dinitrobenzoate, 5-(NO2)sal(-) = 5-nitrosalicylate, bipy = 2,2'-bipyridine and phen = 1,10-phenanthroline, exhibits the syn-anti bidentate bridging mode. The Mn(II) atom in the coordination polymer [Mn(mu-4-NO(2)bz)(4-NO(2)bz)(phen)(H2O)](n), where 4-NO(2)b(z) = 3-nitrobenzoate, is coordinated by terminal carboxylato groups in the syn monodentate mode but two Mn(II) atoms are connected with bridging 4-nitrobenzoate ligands in the anti-anti bidentate bridging mode. The magnetic susceptibility and magnetization data confirm that weak exchange interactions of an antiferromagnetic nature apply in these complexes.
- Five polymeric Mn(II) complexes with bridging carboxylato groups were prepared and structurally characterized. The bridging carboxylato ligand in double-chain coordination polymeric structures of [Mn(mu-3-NO(2)bz)(2) (bipy)](n)center dot nH(2)O, [Mn(mu-3,5-(NO2)(2)bz)(2)(bipy)](n), [Mn(mu-5-(NO2)sal)(2)(bipy)](n), and [Mn(mu-5-(NO2)sal)(2)(phen)](n), where 3-NO(2)bz(-) = 3-nitrobenzoate, 3,5-(NO2)(2)bz(-) = 3,5-dinitrobenzoate, 5-(NO2)sal(-) = 5-nitrosalicylate, bipy = 2,2'-bipyridine and phen = 1,10-phenanthroline, exhibits the syn-anti bidentate bridging mode. The Mn(II) atom in the coordination polymer [Mn(mu-4-NO(2)bz)(4-NO(2)bz)(phen)(H2O)](n), where 4-NO(2)b(z) = 3-nitrobenzoate, is coordinated by terminal carboxylato groups in the syn monodentate mode but two Mn(II) atoms are connected with bridging 4-nitrobenzoate ligands in the anti-anti bidentate bridging mode. The magnetic susceptibility and magnetization data confirm that weak exchange interactions of an antiferromagnetic nature apply in these complexes. (en)
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Title
| - Manganese(II) one-dimensional coordination polymers with nitrobenzoato or nitrosalicylato bridges: Syntheses, crystal structures, and magnetic properties
- Manganese(II) one-dimensional coordination polymers with nitrobenzoato or nitrosalicylato bridges: Syntheses, crystal structures, and magnetic properties (en)
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skos:prefLabel
| - Manganese(II) one-dimensional coordination polymers with nitrobenzoato or nitrosalicylato bridges: Syntheses, crystal structures, and magnetic properties
- Manganese(II) one-dimensional coordination polymers with nitrobenzoato or nitrosalicylato bridges: Syntheses, crystal structures, and magnetic properties (en)
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skos:notation
| - RIV/00216275:25310/14:39898441!RIV15-MSM-25310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/14:39898441
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Coordination polymer; EPR spectroscopy; Magnetic properties; Crystal structures; Manganese (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Moncol, Jan
- Padělková, Zdeňka
- Valigura, Dusan
- Valko, Marian
- Boca, Roman
- Cechova, Danica
- Dlhan, L'ubor
- Gala, Lukas
- Martiskova, Alena
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1016/j.poly.2014.05.005
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http://localhost/t...ganizacniJednotka
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