| Attributes | Values |
|---|
| rdf:type
| |
| Description
| - The synthesis and structure of lanthanide(III) amides containing one bifunctional beta-diketiminate ligand is reported. Compounds were obtained via a protolytic reaction of the free beta-diketimine {N-[(2-MeO) C6H5]}N=C(Me)CH=C(Me)N(H){N '-[(2-MeO)C6H5]} ((LH)-H-CO) or {N-[(2-MeO)C6H5]}N=CHCH=CHN(H) {N '-[(2-MeO)C6H5]} ((LH)-H-HO) with corresponding tris(amide) of the Ln[N(SiMe3)(2)](3) (Ln = Y, La, Nd, Sm, Eu, Gd and Yb) type in equimolar ratio at ambient temperature. Products were characterized by IR and/or multinuclear NMR spectroscopy techniques and structures of four of them have been determined by X-ray diffraction techniques. Complexes (LY)-Y-CO[N( SiMe3)(2)](2), (LLa)-La-CO[N(SiMe3)(2)](2), (LNd)-Nd-CO[N(SiMe3)(2)](2) and (LYb)-Yb-HO [N(SiMe3)(2)](2) crystalize as monomers with the six-coordinated metal centre by two amido and one tetradentate beta-diketiminato ligands. Minor hydrolytic products of composition [(LSmN)-Sm-CO(SiMe3)(2)](2)O and (L-CO)(4)O-2(OH)(4)La-4 were obtained and their structures contain two or four lanthanide atoms linked through the oxo- or hydroxo bridges. Diamagnetic complexes were tested for its potential applications in hydroamination and polymerization reactions, respectively, giving low conversion in all reactions.
- The synthesis and structure of lanthanide(III) amides containing one bifunctional beta-diketiminate ligand is reported. Compounds were obtained via a protolytic reaction of the free beta-diketimine {N-[(2-MeO) C6H5]}N=C(Me)CH=C(Me)N(H){N '-[(2-MeO)C6H5]} ((LH)-H-CO) or {N-[(2-MeO)C6H5]}N=CHCH=CHN(H) {N '-[(2-MeO)C6H5]} ((LH)-H-HO) with corresponding tris(amide) of the Ln[N(SiMe3)(2)](3) (Ln = Y, La, Nd, Sm, Eu, Gd and Yb) type in equimolar ratio at ambient temperature. Products were characterized by IR and/or multinuclear NMR spectroscopy techniques and structures of four of them have been determined by X-ray diffraction techniques. Complexes (LY)-Y-CO[N( SiMe3)(2)](2), (LLa)-La-CO[N(SiMe3)(2)](2), (LNd)-Nd-CO[N(SiMe3)(2)](2) and (LYb)-Yb-HO [N(SiMe3)(2)](2) crystalize as monomers with the six-coordinated metal centre by two amido and one tetradentate beta-diketiminato ligands. Minor hydrolytic products of composition [(LSmN)-Sm-CO(SiMe3)(2)](2)O and (L-CO)(4)O-2(OH)(4)La-4 were obtained and their structures contain two or four lanthanide atoms linked through the oxo- or hydroxo bridges. Diamagnetic complexes were tested for its potential applications in hydroamination and polymerization reactions, respectively, giving low conversion in all reactions. (en)
|
| Title
| - Structure and potential applications of amido lanthanide complexes chelated by bifunctional beta-diketiminate ligand
- Structure and potential applications of amido lanthanide complexes chelated by bifunctional beta-diketiminate ligand (en)
|
| skos:prefLabel
| - Structure and potential applications of amido lanthanide complexes chelated by bifunctional beta-diketiminate ligand
- Structure and potential applications of amido lanthanide complexes chelated by bifunctional beta-diketiminate ligand (en)
|
| skos:notation
| - RIV/00216275:25310/14:39898436!RIV15-GA0-25310___
|
| http://linked.open...avai/riv/aktivita
| |
| http://linked.open...avai/riv/aktivity
| |
| http://linked.open...iv/cisloPeriodika
| |
| http://linked.open...vai/riv/dodaniDat
| |
| http://linked.open...aciTvurceVysledku
| |
| http://linked.open.../riv/druhVysledku
| |
| http://linked.open...iv/duvernostUdaju
| |
| http://linked.open...titaPredkladatele
| |
| http://linked.open...dnocenehoVysledku
| |
| http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/14:39898436
|
| http://linked.open...riv/jazykVysledku
| |
| http://linked.open.../riv/klicovaSlova
| - Polymerization; Hydroamination; Lanthanides; Bifunctional beta-diketiminates (en)
|
| http://linked.open.../riv/klicoveSlovo
| |
| http://linked.open...odStatuVydavatele
| - CH - Švýcarská konfederace
|
| http://linked.open...ontrolniKodProRIV
| |
| http://linked.open...i/riv/nazevZdroje
| - Journal of Organometallic Chemistry
|
| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
| |
| http://linked.open...vavai/riv/projekt
| |
| http://linked.open...UplatneniVysledku
| |
| http://linked.open...v/svazekPeriodika
| |
| http://linked.open...iv/tvurceVysledku
| - Padělková, Zdeňka
- Růžička, Aleš
- Horáček, Michal
- Merna, Jan
- Olejník, Roman
- Fridrichová, Adéla
|
| http://linked.open...ain/vavai/riv/wos
| |
| issn
| |
| number of pages
| |
| http://bibframe.org/vocab/doi
| - 10.1016/j.jorganchem.2014.02.007
|
| http://localhost/t...ganizacniJednotka
| |
![[RDF Data]](/fct/images/sw-rdf-blue.png)
![[cxml]](/fct/images/cxml_doc.png)
![[csv]](/fct/images/csv_doc.png)
![[text]](/fct/images/ntriples_doc.png)
![[turtle]](/fct/images/n3turtle_doc.png)
![[ld+json]](/fct/images/jsonld_doc.png)
![[rdf+json]](/fct/images/json_doc.png)
![[rdf+xml]](/fct/images/xml_doc.png)
![[atom+xml]](/fct/images/atom_doc.png)
![[html]](/fct/images/html_doc.png)