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| Description
| - A series of new acyl-functionalized molybdenum(II) complexes [(éta3-C3H5)(éta5-C5H4COR)Mo(CO)2] have been successfully synthesized and crystallographically characterized, and the relationship between the reactivity and electronic properties of these organometallic compounds has been studied in detail. The X-ray analysis revealed [(éta3-C3H5)(éta5-C5H4COCF3)Mo(CO)2] to exist as a rare endo conformer, the first time that this structure has been observed in the crystal lattice of a [(éta3-C3H5)(éta5-Cp?)Mo(CO)2] (Cp? = substituted Cp) complex without any disorder. It has also been demonstrated that the derivatives bearing very strong electron-withdrawing acyl groups (e.g., -CHO, -COCF3) show different outcomes in the protonation reactions compared with the parent cyclopentadienyl compound or derivatives bearing less electron-withdrawing groups (e.g., -COMe, -COPh). This study has also revealed the increased reactivity of the formyl derivative [(éta3-C3H5)(éta5-C5H4CHO)Mo(CO)2] towards aromatic amines. An IR spectroscopic analysis revealed that the aldimine-functionalized products formed very quickly even under the mild conditions that fulfill the basic rules of click chemistry.
- A series of new acyl-functionalized molybdenum(II) complexes [(éta3-C3H5)(éta5-C5H4COR)Mo(CO)2] have been successfully synthesized and crystallographically characterized, and the relationship between the reactivity and electronic properties of these organometallic compounds has been studied in detail. The X-ray analysis revealed [(éta3-C3H5)(éta5-C5H4COCF3)Mo(CO)2] to exist as a rare endo conformer, the first time that this structure has been observed in the crystal lattice of a [(éta3-C3H5)(éta5-Cp?)Mo(CO)2] (Cp? = substituted Cp) complex without any disorder. It has also been demonstrated that the derivatives bearing very strong electron-withdrawing acyl groups (e.g., -CHO, -COCF3) show different outcomes in the protonation reactions compared with the parent cyclopentadienyl compound or derivatives bearing less electron-withdrawing groups (e.g., -COMe, -COPh). This study has also revealed the increased reactivity of the formyl derivative [(éta3-C3H5)(éta5-C5H4CHO)Mo(CO)2] towards aromatic amines. An IR spectroscopic analysis revealed that the aldimine-functionalized products formed very quickly even under the mild conditions that fulfill the basic rules of click chemistry. (en)
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| Title
| - Acyl-Functionalized Molybdenum Compounds [(éta3-C3H5)(éta5-Cp)Mo(CO)2]: An Experimental Study Including the X-ray Structure of a Rare endo Conformer
- Acyl-Functionalized Molybdenum Compounds [(éta3-C3H5)(éta5-Cp)Mo(CO)2]: An Experimental Study Including the X-ray Structure of a Rare endo Conformer (en)
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| skos:prefLabel
| - Acyl-Functionalized Molybdenum Compounds [(éta3-C3H5)(éta5-Cp)Mo(CO)2]: An Experimental Study Including the X-ray Structure of a Rare endo Conformer
- Acyl-Functionalized Molybdenum Compounds [(éta3-C3H5)(éta5-Cp)Mo(CO)2]: An Experimental Study Including the X-ray Structure of a Rare endo Conformer (en)
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| skos:notation
| - RIV/00216275:25310/14:39898091!RIV15-MSM-25310___
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| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
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| http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/14:39898091
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| http://linked.open...riv/jazykVysledku
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| http://linked.open.../riv/klicovaSlova
| - Raman spectroscopy; IR spectroscopy; Ligand effects; Molybdenum; Sandwich complexes (en)
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| http://linked.open.../riv/klicoveSlovo
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| http://linked.open...odStatuVydavatele
| - DE - Spolková republika Německo
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| http://linked.open...ontrolniKodProRIV
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| http://linked.open...i/riv/nazevZdroje
| - European Journal of Inorganic Chemistry
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| http://linked.open...in/vavai/riv/obor
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| http://linked.open...ichTvurcuVysledku
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| http://linked.open...cetTvurcuVysledku
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| http://linked.open...UplatneniVysledku
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| http://linked.open...v/svazekPeriodika
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| http://linked.open...iv/tvurceVysledku
| - Erben, Milan
- Vinklárek, Jaromír
- Honzíček, Jan
- Schejbal, Jiří
- Růžičková, Zdeňka
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| http://linked.open...ain/vavai/riv/wos
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| issn
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| number of pages
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| http://bibframe.org/vocab/doi
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| http://localhost/t...ganizacniJednotka
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