About: Large-area inverse opal structures in a bulk chalcogenide glass by spin-coating and thin-film transfer     Goto   Sponge   NotDistinct   Permalink

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Description
  • Large (cm x cm), uniform-thickness areas of an inverse-opal photonic crystal and an inverse-opal monolayer were fabricated in a high-refractive-index As30S70 chalcogenide glass. We have developed an effective low-cost, solution-based process for fabrication of photonic structures in chalcogenide glass from silica-colloidal-crystal thin-film templates (multi- and monolayer). The chalcogenide-glass solution is spin-coated over the silica-opal film template and the infilled composite structure (chalcogenide/opal) is then lifted-off and transferred onto the chalcogenide-glass disc at 225 C, followed by removal of the template in hydrofluoric acid. The extra step introduced in this work (lift-off and transfer) allows a reproducible and large-area structure to be fabricated on a bulk chalcogenide glass. Complete infilling of the silica template is possible due to the nano-colloidal nature (particle size 2-8 nm) of the chalcogenide-glass solution and effective solvent release from the spin-coated chalcogenide film during post-annealing. The resulting chalcogenide-glass inverse-opal multilayer exhibits a Bragg peak at 670 nm with a reflectance 70%, while the inverse-opal monolayer shows anti-reflectance behaviour {2% in the near-infrared region (1215-1660 nm).
  • Large (cm x cm), uniform-thickness areas of an inverse-opal photonic crystal and an inverse-opal monolayer were fabricated in a high-refractive-index As30S70 chalcogenide glass. We have developed an effective low-cost, solution-based process for fabrication of photonic structures in chalcogenide glass from silica-colloidal-crystal thin-film templates (multi- and monolayer). The chalcogenide-glass solution is spin-coated over the silica-opal film template and the infilled composite structure (chalcogenide/opal) is then lifted-off and transferred onto the chalcogenide-glass disc at 225 C, followed by removal of the template in hydrofluoric acid. The extra step introduced in this work (lift-off and transfer) allows a reproducible and large-area structure to be fabricated on a bulk chalcogenide glass. Complete infilling of the silica template is possible due to the nano-colloidal nature (particle size 2-8 nm) of the chalcogenide-glass solution and effective solvent release from the spin-coated chalcogenide film during post-annealing. The resulting chalcogenide-glass inverse-opal multilayer exhibits a Bragg peak at 670 nm with a reflectance 70%, while the inverse-opal monolayer shows anti-reflectance behaviour {2% in the near-infrared region (1215-1660 nm). (en)
Title
  • Large-area inverse opal structures in a bulk chalcogenide glass by spin-coating and thin-film transfer
  • Large-area inverse opal structures in a bulk chalcogenide glass by spin-coating and thin-film transfer (en)
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  • Large-area inverse opal structures in a bulk chalcogenide glass by spin-coating and thin-film transfer
  • Large-area inverse opal structures in a bulk chalcogenide glass by spin-coating and thin-film transfer (en)
skos:notation
  • RIV/00216275:25310/13:39896950!RIV14-MSM-25310___
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  • P(EE2.3.20.0254)
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  • 2
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  • 84316
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  • RIV/00216275:25310/13:39896950
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  • spin-coating; photonic structures; inverse opal; chalcogenide glasses (en)
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  • NL - Nizozemsko
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  • [1BD68E347850]
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  • Optical Materials
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  • 36
http://linked.open...iv/tvurceVysledku
  • Kohoutek, Tomáš
  • Orava, Jiří
  • Wágner, Tomáš
  • Střižík, Lukáš
  • Greer, A. L.
  • Bardosova, M.
  • Fudouzi, H.
http://linked.open...ain/vavai/riv/wos
  • 000329892000041
issn
  • 0925-3467
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.optmat.2013.09.026
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  • 25310
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