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Description
| - Recent achievements in the chemistry of selected group 13 ? 15 elements con-taining pincer type coordinating ligands are summarized. This chapter covers chemistry of heavier elements Ga, In Tl form the group 13, Ge, Sn, Pb ? especially low valent compounds with formal oxidation state +II or +I and their reactivity from the group 14 and As, Sb, Bi from the group 15. Only the classical pincer type ligands containing nitrogen or oxygen atoms as in-built donor functionalities are considered i.e. 2,6-(R2NCH2)2C6H3 (LN1), 2,6-(ArN=C(CH3))2C6H3 (LN2), 2,6-(ROCH2)C6H3 (LO1, 2, R = Me, t-Bu), 2-(Me2NCH2)-6-(ROCH2)C6H3 (LNO1,2, R = Me, t-Bu), 2,6-((RO)2P(O))2-4-(t-Bu)C6H3 (LPO). The influence of the present pincer ligands on the structures of the compounds as well as their key role in the stabilization of these compounds is discussed.
- Recent achievements in the chemistry of selected group 13 ? 15 elements con-taining pincer type coordinating ligands are summarized. This chapter covers chemistry of heavier elements Ga, In Tl form the group 13, Ge, Sn, Pb ? especially low valent compounds with formal oxidation state +II or +I and their reactivity from the group 14 and As, Sb, Bi from the group 15. Only the classical pincer type ligands containing nitrogen or oxygen atoms as in-built donor functionalities are considered i.e. 2,6-(R2NCH2)2C6H3 (LN1), 2,6-(ArN=C(CH3))2C6H3 (LN2), 2,6-(ROCH2)C6H3 (LO1, 2, R = Me, t-Bu), 2-(Me2NCH2)-6-(ROCH2)C6H3 (LNO1,2, R = Me, t-Bu), 2,6-((RO)2P(O))2-4-(t-Bu)C6H3 (LPO). The influence of the present pincer ligands on the structures of the compounds as well as their key role in the stabilization of these compounds is discussed. (en)
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Title
| - The chemistry of pincer complexes of 13 - 15 main group elements
- The chemistry of pincer complexes of 13 - 15 main group elements (en)
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skos:prefLabel
| - The chemistry of pincer complexes of 13 - 15 main group elements
- The chemistry of pincer complexes of 13 - 15 main group elements (en)
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skos:notation
| - RIV/00216275:25310/13:39896814!RIV14-GA0-25310___
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http://linked.open...avai/predkladatel
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/13:39896814
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - 13-15 Main Group Elements; Pincer Complexes; Organometallic (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - DE - Spolková republika Německo
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Topics in Organometallic Chemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Dostál, Libor
- Jambor, Roman
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1007/978-3-642-31081-2
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http://localhost/t...ganizacniJednotka
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