About: The Effect of Thermal Pre-Treatment on Structure, Composition, Basicity and Catalytic Activity of Mg/Al Mixed Oxides     Goto   Sponge   NotDistinct   Permalink

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Description
  • The goal of this work is to study the effect of thermal pre-treatment of Mg/Al mixed oxides (450-1,050 A degrees C) on their structure, basicity and catalytic activity in transesterification of rapeseed oil. The catalytic activity of Mg/Al catalysts was shown to depend not only on the amount of basic sites, but also on crystallite size of MgO, specific surface area and population of medium/strong basic sites. Moreover, high stability of Mg/Al-550 was established by re-using the catalyst four times. It was associated with negligible magnesium leaching from the solid catalyst to liquid phases.
  • The goal of this work is to study the effect of thermal pre-treatment of Mg/Al mixed oxides (450-1,050 A degrees C) on their structure, basicity and catalytic activity in transesterification of rapeseed oil. The catalytic activity of Mg/Al catalysts was shown to depend not only on the amount of basic sites, but also on crystallite size of MgO, specific surface area and population of medium/strong basic sites. Moreover, high stability of Mg/Al-550 was established by re-using the catalyst four times. It was associated with negligible magnesium leaching from the solid catalyst to liquid phases. (en)
Title
  • The Effect of Thermal Pre-Treatment on Structure, Composition, Basicity and Catalytic Activity of Mg/Al Mixed Oxides
  • The Effect of Thermal Pre-Treatment on Structure, Composition, Basicity and Catalytic Activity of Mg/Al Mixed Oxides (en)
skos:prefLabel
  • The Effect of Thermal Pre-Treatment on Structure, Composition, Basicity and Catalytic Activity of Mg/Al Mixed Oxides
  • The Effect of Thermal Pre-Treatment on Structure, Composition, Basicity and Catalytic Activity of Mg/Al Mixed Oxides (en)
skos:notation
  • RIV/00216275:25310/13:39896424!RIV14-GA0-25310___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • P(ED2.1.00/03.0071), P(EE2.3.30.0058), P(GAP106/11/0773)
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  • 9-10
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  • 71813
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  • RIV/00216275:25310/13:39896424
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  • transesterification; thermal pre-treatment; basic sites; structure analysis; Mg/Al mixed oxides (en)
http://linked.open.../riv/klicoveSlovo
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  • NL - Nizozemsko
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  • [CE05776FC872]
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  • Topics in Catalysis
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  • 56
http://linked.open...iv/tvurceVysledku
  • Kubička, David
  • Smoláková, Lucie
  • Troppová, Ivana
  • Čapek, Libor
  • Hájek, Martin
  • Kutálek, Petr
http://linked.open...ain/vavai/riv/wos
  • 000320500200010
issn
  • 1022-5528
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s11244-013-0008-3
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  • 25310
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