About: High temperature pretreatment of Fe-silicalite for the ammoxidation of propane

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: High temperature pretreatment of Fe-silicalite for the ammoxidation of propane Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://www.sciencedirect.com/science/article/pii/S0920586112005482
Description	Fe-silicalite with low concentration of iron was used in the study of the activation by high temperature nitridation (in the temperature range from 540 degrees C to 700 degrees C). Nitrided materials were characterized by means of FTIR and UV-Vis spectroscopy. It was found out, that by this high temperature pretreatment, Fe-silicalite undergoes structural changes - iron is extracted to extraframework positions and atom of nitrogen is incorporated into the zeolite structure (either as amide or as imide group), which was confirmed by FTIR spectroscopy. Catalytic performance of nitrided materials together with Fe-silicalite activated by hydrothermal pretreatment was studied and compared in the direct ammoxidation of propane. It was found out, that the nitrided materials reaches better results compared to sample activated in the steam. Selectivity as high as 34% at 32% conversion of propane was reached over the sample activated at 600 degrees C by nitridation. Nitrided material showed stable catalytic performance in the TOS study for 10 h. Fe-silicalite with low concentration of iron was used in the study of the activation by high temperature nitridation (in the temperature range from 540 degrees C to 700 degrees C). Nitrided materials were characterized by means of FTIR and UV-Vis spectroscopy. It was found out, that by this high temperature pretreatment, Fe-silicalite undergoes structural changes - iron is extracted to extraframework positions and atom of nitrogen is incorporated into the zeolite structure (either as amide or as imide group), which was confirmed by FTIR spectroscopy. Catalytic performance of nitrided materials together with Fe-silicalite activated by hydrothermal pretreatment was studied and compared in the direct ammoxidation of propane. It was found out, that the nitrided materials reaches better results compared to sample activated in the steam. Selectivity as high as 34% at 32% conversion of propane was reached over the sample activated at 600 degrees C by nitridation. Nitrided material showed stable catalytic performance in the TOS study for 10 h. (en)
Title	High temperature pretreatment of Fe-silicalite for the ammoxidation of propane High temperature pretreatment of Fe-silicalite for the ammoxidation of propane (en)
skos:prefLabel	High temperature pretreatment of Fe-silicalite for the ammoxidation of propane High temperature pretreatment of Fe-silicalite for the ammoxidation of propane (en)
skos:notation	RIV/00216275:25310/13:39896420!RIV14-GA0-25310___
http://linked.open...avai/predkladatel	Fakulta chemicko-technologická
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(GBP106/12/G015), P(GPP106/12/P083)
http://linked.open...iv/cisloPeriodika	April
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Baďurová, Eva Raabová, Kateřina Bulánek, Roman
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	77370
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/13:39896420
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	amide/imide species; propane; ammoxidation; Fe-silicalite; nitridation (en)
http://linked.open.../riv/klicoveSlovo	ammoxidation propane Fe-silicalite amide/imide species nitridation
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[09F31D5675DC]
http://linked.open...i/riv/nazevZdroje	Catalysis Today
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Intelligent design of nanoporous adsorbents and catalysts The study of the catalytic activity of the Fe-zeolites in the direct ammoxidation of propane
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	204
http://linked.open...iv/tvurceVysledku	Bulánek, Roman Raabová, Kateřina Priecel Baďurová, Eva
http://linked.open...ain/vavai/riv/wos	000314825900009
issn	0920-5861
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.cattod.2012.06.035
http://localhost/t...ganizacniJednotka	25310

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 58 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software