Attributes | Values |
---|
rdf:type
| |
rdfs:seeAlso
| |
Description
| - Treatment of the neutral 2-[C(CH3)=N(C6H3-2,6-Pr-i(2))]-6-(CH3O)C6H3N ligand (hereafter assigned as L) with SnCl2 and GeCl2 provided the ionic germanium(II) and tin(II) complexes [(LGeCl)-Cl-II](+)[(GeCl3)-Cl-II](-) (1) and [(LSnCl)-Cl-II](+)[(SnCl3)-Cl-II](-) (2), respectively, as the result of spontaneous dissociation of ECl2 (E = Ge, Sn). The cationic parts [(LECl)-Cl-II](+) of 1 and 2 contain three-coordinated germanium(II) and tin(II) atoms. In comparison, treatment of the ligand L with GeCl4, and SnBr4 yielded the germanium(IV) and tin(IV) complexes LGeCl4 (3) and LSnBr4 (4), respectively, and no dissociation process was observed. Compounds 1-4 were characterized by means of elemental analyses, H-1, C-13, and Sn-119 NMR spectroscopies, and single-crystal X-ray diffraction analysis in (compounds 1 and 4).
- Treatment of the neutral 2-[C(CH3)=N(C6H3-2,6-Pr-i(2))]-6-(CH3O)C6H3N ligand (hereafter assigned as L) with SnCl2 and GeCl2 provided the ionic germanium(II) and tin(II) complexes [(LGeCl)-Cl-II](+)[(GeCl3)-Cl-II](-) (1) and [(LSnCl)-Cl-II](+)[(SnCl3)-Cl-II](-) (2), respectively, as the result of spontaneous dissociation of ECl2 (E = Ge, Sn). The cationic parts [(LECl)-Cl-II](+) of 1 and 2 contain three-coordinated germanium(II) and tin(II) atoms. In comparison, treatment of the ligand L with GeCl4, and SnBr4 yielded the germanium(IV) and tin(IV) complexes LGeCl4 (3) and LSnBr4 (4), respectively, and no dissociation process was observed. Compounds 1-4 were characterized by means of elemental analyses, H-1, C-13, and Sn-119 NMR spectroscopies, and single-crystal X-ray diffraction analysis in (compounds 1 and 4). (en)
|
Title
| - Stabilization of Three-Coordinated Germanium(II) and Tin(II) Cations by a Neutral Chelating Ligand
- Stabilization of Three-Coordinated Germanium(II) and Tin(II) Cations by a Neutral Chelating Ligand (en)
|
skos:prefLabel
| - Stabilization of Three-Coordinated Germanium(II) and Tin(II) Cations by a Neutral Chelating Ligand
- Stabilization of Three-Coordinated Germanium(II) and Tin(II) Cations by a Neutral Chelating Ligand (en)
|
skos:notation
| - RIV/00216275:25310/13:39896296!RIV14-MSM-25310___
|
http://linked.open...avai/predkladatel
| |
http://linked.open...avai/riv/aktivita
| |
http://linked.open...avai/riv/aktivity
| |
http://linked.open...iv/cisloPeriodika
| |
http://linked.open...vai/riv/dodaniDat
| |
http://linked.open...aciTvurceVysledku
| |
http://linked.open.../riv/druhVysledku
| |
http://linked.open...iv/duvernostUdaju
| |
http://linked.open...titaPredkladatele
| |
http://linked.open...dnocenehoVysledku
| |
http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/13:39896296
|
http://linked.open...riv/jazykVysledku
| |
http://linked.open.../riv/klicovaSlova
| - activation; coordination; complexes; tin cations (en)
|
http://linked.open.../riv/klicoveSlovo
| |
http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
|
http://linked.open...ontrolniKodProRIV
| |
http://linked.open...i/riv/nazevZdroje
| |
http://linked.open...in/vavai/riv/obor
| |
http://linked.open...ichTvurcuVysledku
| |
http://linked.open...cetTvurcuVysledku
| |
http://linked.open...UplatneniVysledku
| |
http://linked.open...v/svazekPeriodika
| |
http://linked.open...iv/tvurceVysledku
| - Dostál, Libor
- Jambor, Roman
- Růžička, Aleš
- Bouška, Marek
|
http://linked.open...ain/vavai/riv/wos
| |
issn
| |
number of pages
| |
http://bibframe.org/vocab/doi
| |
http://localhost/t...ganizacniJednotka
| |