About: Silver environment and covalent network rearrangement in GeS3-Ag glasses     Goto   Sponge   NotDistinct   Permalink

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  • The structure of Ag-doped GeS3 glasses (0, 15, 20, 25 at.% Ag) was investigated by diffraction techniques and extended x-ray absorption fine structure measurements. Structural models were obtained by fitting the experimental datasets simultaneously by the reverse Monte Carlo simulation technique. It is observed that Ge has mostly S neighbours in GeS3, but Ge-Ge bonds appear already at 15% Ag content. Sulfur has similar to 2 S/Ge neighbours over the whole concentration range, while the S-Ag coordination number increases with increasing Ag content. Ag-Ag pairs can already be found at 15% Ag. The Ag-S mean coordination number changes from 2.17 +/- 0.2 to 2.86 +/- 0.2 between 15% and 25% Ag content. Unlike the As-S network in AsS2-25Ag glass, the Ge-S network is not fragmented upon Ag-doping of GeS3 glass.
  • The structure of Ag-doped GeS3 glasses (0, 15, 20, 25 at.% Ag) was investigated by diffraction techniques and extended x-ray absorption fine structure measurements. Structural models were obtained by fitting the experimental datasets simultaneously by the reverse Monte Carlo simulation technique. It is observed that Ge has mostly S neighbours in GeS3, but Ge-Ge bonds appear already at 15% Ag content. Sulfur has similar to 2 S/Ge neighbours over the whole concentration range, while the S-Ag coordination number increases with increasing Ag content. Ag-Ag pairs can already be found at 15% Ag. The Ag-S mean coordination number changes from 2.17 +/- 0.2 to 2.86 +/- 0.2 between 15% and 25% Ag content. Unlike the As-S network in AsS2-25Ag glass, the Ge-S network is not fragmented upon Ag-doping of GeS3 glass. (en)
Title
  • Silver environment and covalent network rearrangement in GeS3-Ag glasses
  • Silver environment and covalent network rearrangement in GeS3-Ag glasses (en)
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  • Silver environment and covalent network rearrangement in GeS3-Ag glasses
  • Silver environment and covalent network rearrangement in GeS3-Ag glasses (en)
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  • RIV/00216275:25310/13:39896217!RIV14-MSM-25310___
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  • P(EE2.3.20.0254)
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  • 45
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  • 105081
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  • RIV/00216275:25310/13:39896217
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  • ag; range; spectra; neutron; scattering; reverse; disordered structures; fine-structure; chalcogenide glasses; x-ray-diffraction (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [D7F7A8394E19]
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  • Journal of Physics-Condensed Matter
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  • 25
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  • Voleská, Iva
  • Wágner, Tomáš
  • Kolář, Jakub
  • Beuneu, B.
  • Kaban, I.
  • Jovari, P.
  • Ratkai, L.
  • Valkova, Silviya
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  • 000325919400011
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  • 0953-8984
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  • 10.1088/0953-8984/25/45/454210
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  • 25310
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