About: Enantiocatalytic activity of substituted 5-benzyl-2-(pyridine-2-yl)imidazolidine-4-one ligands     Goto   Sponge   NotDistinct   Permalink

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Description
  • The substituted 5-benzyl-2-(pyridine-2-yl)imidazolidine-4- ones were prepared by condensation of chiral amino acid amides (?-methylDOPA and ?-methylphenylalanine) with 2-acetylpyridine and pyridine-2-carbaldehyde. The prepared copper(II) of these chiral ligands were studied as enantioselective catalysts for the asymmetric Henry reaction of substituted aldehydes with nitromethane or nitroethane.
  • The substituted 5-benzyl-2-(pyridine-2-yl)imidazolidine-4- ones were prepared by condensation of chiral amino acid amides (?-methylDOPA and ?-methylphenylalanine) with 2-acetylpyridine and pyridine-2-carbaldehyde. The prepared copper(II) of these chiral ligands were studied as enantioselective catalysts for the asymmetric Henry reaction of substituted aldehydes with nitromethane or nitroethane. (en)
Title
  • Enantiocatalytic activity of substituted 5-benzyl-2-(pyridine-2-yl)imidazolidine-4-one ligands
  • Enantiocatalytic activity of substituted 5-benzyl-2-(pyridine-2-yl)imidazolidine-4-one ligands (en)
skos:prefLabel
  • Enantiocatalytic activity of substituted 5-benzyl-2-(pyridine-2-yl)imidazolidine-4-one ligands
  • Enantiocatalytic activity of substituted 5-benzyl-2-(pyridine-2-yl)imidazolidine-4-one ligands (en)
skos:notation
  • RIV/00216275:25310/13:39896113!RIV14-MSM-25310___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • P(EE2.3.30.0021), S
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  • 5-6
http://linked.open...vai/riv/dodaniDat
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  • 72743
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  • RIV/00216275:25310/13:39896113
http://linked.open...riv/jazykVysledku
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  • CATALYSIS; RESOLUTION; ALDEHYDES; CU-II; COPPER(II) COMPLEXES; NITROALDOL REACTIONS; ASYMMETRIC HENRY REACTION (en)
http://linked.open.../riv/klicoveSlovo
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  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [9D92BA676F7C]
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  • Tetrahedron Asymmetry
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http://linked.open...v/svazekPeriodika
  • 24
http://linked.open...iv/tvurceVysledku
  • Drabina, Pavel
  • Panov, Illia
  • Sedlák, Miloš
  • Karel, Sergej
http://linked.open...ain/vavai/riv/wos
  • 000316843000014
issn
  • 0957-4166
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.tetasy.2013.02.007
http://localhost/t...ganizacniJednotka
  • 25310
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