About: Skeletal alkylcarbonation (SAC) reactions as a simple design for cluster-carbon insertion and cross-coupling: high-yield access to substituted tricarbollides from 6,9-dicarba-arachno-decaborane(14)

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About: Skeletal alkylcarbonation (SAC) reactions as a simple design for cluster-carbon insertion and cross-coupling: high-yield access to substituted tricarbollides from 6,9-dicarba-arachno-decaborane(14) Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://onlinelibrary.wiley.com/doi/10.1002/chem.201102016/pdf
Description	A simple and high-yield route to a series of tricarbollide compounds 8-R-nido-7,8,9-C3B8H11 and [8-R-nido-7,8,9-C3B8H10]? (exemplified by R=Me, Ph, and 1-naphthyl) was developed. The method is based on a new type of C-insertion cross-coupling through skeletal alkylcarbonation (SAC) reactions between acyl chlorides (RCOCl) and the arachno-6,9-C2B8H14 carborane. A simple and high-yield route to a series of tricarbollide compounds 8-R-nido-7,8,9-C3B8H11 and [8-R-nido-7,8,9-C3B8H10]? (exemplified by R=Me, Ph, and 1-naphthyl) was developed. The method is based on a new type of C-insertion cross-coupling through skeletal alkylcarbonation (SAC) reactions between acyl chlorides (RCOCl) and the arachno-6,9-C2B8H14 carborane. (en)
Title	Skeletal alkylcarbonation (SAC) reactions as a simple design for cluster-carbon insertion and cross-coupling: high-yield access to substituted tricarbollides from 6,9-dicarba-arachno-decaborane(14) Skeletal alkylcarbonation (SAC) reactions as a simple design for cluster-carbon insertion and cross-coupling: high-yield access to substituted tricarbollides from 6,9-dicarba-arachno-decaborane(14) (en)
skos:prefLabel	Skeletal alkylcarbonation (SAC) reactions as a simple design for cluster-carbon insertion and cross-coupling: high-yield access to substituted tricarbollides from 6,9-dicarba-arachno-decaborane(14) Skeletal alkylcarbonation (SAC) reactions as a simple design for cluster-carbon insertion and cross-coupling: high-yield access to substituted tricarbollides from 6,9-dicarba-arachno-decaborane(14) (en)
skos:notation	RIV/00216275:25310/12:39895760!RIV13-GA0-25310___
http://linked.open...avai/predkladatel	Fakulta chemicko-technologická
http://linked.open...avai/riv/aktivita	I P S Z
http://linked.open...avai/riv/aktivity	I, P(GAP207/11/0705), P(LC523), S, Z(AV0Z40320502), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	47
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Růžička, Aleš Padělková, Zdeňka Olejník, Roman
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	229632
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/12:39895760
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	synthetic methods; cross-coupling; carboranes; boranes; acyl chlorides (en)
http://linked.open.../riv/klicoveSlovo	boranes cross-coupling acyl chlorides synthetic methods carboranes
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[1DF4B58A2D74]
http://linked.open...i/riv/nazevZdroje	Chemistry - A European Journal
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials Carborane-modified iron-arene complexes
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	17
http://linked.open...iv/tvurceVysledku	Bakardjiev, Mario Holub, Josef Padělková, Zdeňka Růžička, Aleš Štíbr, Bohumil Švec, Petr Olejník, Roman
http://linked.open...ain/vavai/riv/wos	000298058500009
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	0947-6539
number of pages	4 (xsd:int)
http://bibframe.org/vocab/doi	10.1002/chem.201102016
http://localhost/t...ganizacniJednotka	25310
is http://linked.open...avai/riv/vysledek of	Skeletal alkylcarbonation (SAC) reactions as a simple design for cluster-carbon insertion and cross-coupling: high-yield access to substituted tricarbollides from 6,9-dicarba-arachno-decaborane(14)

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