About: Comprehensive Two-Dimensional Liquid Chromatography - Practical Impacts of Theoretical Considerations. A Review

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Comprehensive Two-Dimensional Liquid Chromatography - Practical Impacts of Theoretical Considerations. A Review Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A theory of comprehensive two-dimensional separations by liquid chromatographic techniques is overviewed. It includes heart-cutting and comprehensive two-dimensional separation modes, with attention to basic concepts of two-dimensional separations: resolution, peak capacity, efficiency, orthogonality and selectivity. Particular attention is paid to the effects of sample structure on the retention and advantages of a multi-dimensional HPLC for separation of complex samples according to structural correlations. Optimization of 2D separation systems, including correct selection of columns, flow-rate, fraction volumes and mobile phase, is discussed. Benefits of simultaneous programmed elution in both dimensions of LCxLC comprehensive separations are shown. Experimental setup, modulation of the fraction collection and transfer from the first to the second dimension, compatibility of mobile phases in comprehensive LCxLC, 2D asymmetry and shifts in retention under changing second-dimension elution conditions, are addressed. Illustrative practical examples of comprehensive LCxLC separations are shown. A theory of comprehensive two-dimensional separations by liquid chromatographic techniques is overviewed. It includes heart-cutting and comprehensive two-dimensional separation modes, with attention to basic concepts of two-dimensional separations: resolution, peak capacity, efficiency, orthogonality and selectivity. Particular attention is paid to the effects of sample structure on the retention and advantages of a multi-dimensional HPLC for separation of complex samples according to structural correlations. Optimization of 2D separation systems, including correct selection of columns, flow-rate, fraction volumes and mobile phase, is discussed. Benefits of simultaneous programmed elution in both dimensions of LCxLC comprehensive separations are shown. Experimental setup, modulation of the fraction collection and transfer from the first to the second dimension, compatibility of mobile phases in comprehensive LCxLC, 2D asymmetry and shifts in retention under changing second-dimension elution conditions, are addressed. Illustrative practical examples of comprehensive LCxLC separations are shown. (en)
Title	Comprehensive Two-Dimensional Liquid Chromatography - Practical Impacts of Theoretical Considerations. A Review Comprehensive Two-Dimensional Liquid Chromatography - Practical Impacts of Theoretical Considerations. A Review (en)
skos:prefLabel	Comprehensive Two-Dimensional Liquid Chromatography - Practical Impacts of Theoretical Considerations. A Review Comprehensive Two-Dimensional Liquid Chromatography - Practical Impacts of Theoretical Considerations. A Review (en)
skos:notation	RIV/00216275:25310/12:39895682!RIV13-GA0-25310___
http://linked.open...avai/predkladatel	Fakulta chemicko-technologická
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(GA203/07/0641)
http://linked.open...iv/cisloPeriodika	3
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Jandera, Pavel
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	128255
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/12:39895682
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Sample transfer modulation.; Selectivity; Orthogonality; Comprehensive LC; Two-dimensional HPLC (en)
http://linked.open.../riv/klicoveSlovo	Comprehensive LC Sample transfer modulation. Selectivity Two-dimensional HPLC Orthogonality
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[E02BCF8B30C4]
http://linked.open...i/riv/nazevZdroje	Central European Journal of Chemistry
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	1 (xsd:int)
http://linked.open...vavai/riv/projekt	New analytical methods in combined high-capacity phase separation systems
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	10
http://linked.open...iv/tvurceVysledku	Jandera, Pavel
http://linked.open...ain/vavai/riv/wos	000302144400025
issn	1895-1066
number of pages	32 (xsd:int)
http://bibframe.org/vocab/doi	10.2478/s11532-012-0036-z
http://localhost/t...ganizacniJednotka	25310
is http://linked.open...avai/riv/vysledek of	Comprehensive Two-Dimensional Liquid Chromatography - Practical Impacts of Theoretical Considerations. A Review

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 58 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software