About: Electroanalysis with Bismuth- and Antimony-Film Plated Carbon Paste Electrodes in Complex-Forming and Mixed Supporting Media     Goto   Sponge   NotDistinct   Permalink

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  • In this paper, a new study is presented, concerning the possibilities and limitations of bismuth- and antimony-film plated carbon paste electrodes, BiF-CPE and SbF-CPE, in combination with stripping voltammetry and mixed supporting electrolytes containing various complex-forming constituents. The experiments with both BiF-CPE and SbF-CPE in solutions containing halides (F-, Cl-, Br-, I-), pseudohalides (SCN-, CNO-, CN-), EDTA, or organic anions (tartrate, citrate) were focused on electroanalytical performance of both electrodes for the determination of Cd2+ and Pb2+ as model ions. Their behaviour was observed and discussed via the effects of the individual media upon the peak characteristics, base-line, as well as the dissolution peak of Bi/Sb. The results obtained have confirmed numerous relations and typical features that can be utilised in practical measurements.
  • In this paper, a new study is presented, concerning the possibilities and limitations of bismuth- and antimony-film plated carbon paste electrodes, BiF-CPE and SbF-CPE, in combination with stripping voltammetry and mixed supporting electrolytes containing various complex-forming constituents. The experiments with both BiF-CPE and SbF-CPE in solutions containing halides (F-, Cl-, Br-, I-), pseudohalides (SCN-, CNO-, CN-), EDTA, or organic anions (tartrate, citrate) were focused on electroanalytical performance of both electrodes for the determination of Cd2+ and Pb2+ as model ions. Their behaviour was observed and discussed via the effects of the individual media upon the peak characteristics, base-line, as well as the dissolution peak of Bi/Sb. The results obtained have confirmed numerous relations and typical features that can be utilised in practical measurements. (en)
Title
  • Electroanalysis with Bismuth- and Antimony-Film Plated Carbon Paste Electrodes in Complex-Forming and Mixed Supporting Media
  • Electroanalysis with Bismuth- and Antimony-Film Plated Carbon Paste Electrodes in Complex-Forming and Mixed Supporting Media (en)
skos:prefLabel
  • Electroanalysis with Bismuth- and Antimony-Film Plated Carbon Paste Electrodes in Complex-Forming and Mixed Supporting Media
  • Electroanalysis with Bismuth- and Antimony-Film Plated Carbon Paste Electrodes in Complex-Forming and Mixed Supporting Media (en)
skos:notation
  • RIV/00216275:25310/11:39892640!RIV12-MSM-25310___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • P(LC06035), P(MEB091139), Z(MSM0021627502)
http://linked.open...iv/cisloPeriodika
  • prosinec
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 197012
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/11:39892640
http://linked.open...riv/jazykVysledku
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  • Complex-forming media; Antimony film; Bismuth film; Carbon paste electrodes; Electroanalysis (en)
http://linked.open.../riv/klicoveSlovo
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  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [F7026BF8A16B]
http://linked.open...i/riv/nazevZdroje
  • Scientific Papers of the University of Pardubice, Series A, Faculty of Chemical Technology
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 17
http://linked.open...iv/tvurceVysledku
  • Stočes, Matěj
  • Švancara, Ivan
  • Bartoš, Martin
http://linked.open...n/vavai/riv/zamer
issn
  • 1211-5541
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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