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  • This paper is focused on migration of substances (photoinitiators and monomers) from formulations cured by UV radiation. Samples containing only monomer and photoinitiator were cured under different conditions. After evaluation of monomer conversion (FTIR spectroscopy) amount of substances that migrated from cured sample into simulant (acetonitrile) by UV/VIS spectroscopy was estimated. The tested initiators were free radical photoinitiator (1-[4-(2-hydroxyethoxy)-phenyl]-2-hydroxy-2-methylpropan-1-on) and cationic photoinitiator (hepta5-2,4-cyclopentadien-1-yl)-[(1,2,3,4,5,6-hepta)-chlorobenzene]-Fe(II)-hexafluorophosphate). Acrylate binder pentaerythritol triacrylate and epoxy binder (3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane-carboxylate) were used as monomers.
  • This paper is focused on migration of substances (photoinitiators and monomers) from formulations cured by UV radiation. Samples containing only monomer and photoinitiator were cured under different conditions. After evaluation of monomer conversion (FTIR spectroscopy) amount of substances that migrated from cured sample into simulant (acetonitrile) by UV/VIS spectroscopy was estimated. The tested initiators were free radical photoinitiator (1-[4-(2-hydroxyethoxy)-phenyl]-2-hydroxy-2-methylpropan-1-on) and cationic photoinitiator (hepta5-2,4-cyclopentadien-1-yl)-[(1,2,3,4,5,6-hepta)-chlorobenzene]-Fe(II)-hexafluorophosphate). Acrylate binder pentaerythritol triacrylate and epoxy binder (3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane-carboxylate) were used as monomers. (en)
Title
  • The Migration of Substances from Layers Cured by UV Radiation
  • The Migration of Substances from Layers Cured by UV Radiation (en)
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  • The Migration of Substances from Layers Cured by UV Radiation
  • The Migration of Substances from Layers Cured by UV Radiation (en)
skos:notation
  • RIV/00216275:25310/11:39892438!RIV12-MSM-25310___
http://linked.open...avai/predkladatel
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  • S, Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika
  • prosinec
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 212438
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  • RIV/00216275:25310/11:39892438
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  • UV polymerization; migration (en)
http://linked.open.../riv/klicoveSlovo
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  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [219697F3AA6E]
http://linked.open...i/riv/nazevZdroje
  • Scientific Papers of the University of Pardubice, Series A, Faculty of Chemical Technology
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http://linked.open...v/svazekPeriodika
  • 17
http://linked.open...iv/tvurceVysledku
  • Jašúrek, Bohumil
  • Vališ, Jan
  • Bendáková, Nela
http://linked.open...n/vavai/riv/zamer
issn
  • 1211-5541
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  • 25310
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