About: Vanadocene complexes of amino acids containing secondary amino group: The first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety.

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About: Vanadocene complexes of amino acids containing secondary amino group: The first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety. Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Reaction of vanadocene dichlorides (Cp2VCl2 and (C5H4Me)2VCl2) with amino acids containing secondary amino groups gives three types of complexes: a) compounds with N,O-bonded amino acid, b) O-bonded amino acids and c) O,O-bonded amino acid. The complexes with N,O-bonded amino acid and O-bonded amino acids were observed in the case of L-proline and N-methylglycine (NMG). Reactions with N-phenylglycine (NPG) give O,O-chelates as the sole products. All three types of the complexes were characterized by spectroscopic methods. Structures of [(C5H4Me)2V(O-Pro)][BPh4], [Cp2V(O-Pro)2][PF6]2, [Cp2V(N,O-NMG)][BPh4], [(C5H4Me)2V(N,O-NMG)][BPh4], [Cp2V(O-NMG)2][Cl]2, [(C5H4Me)2V(O-NMG)2][Cl]2 and [(C5H4Me)2V(O,O-NPG)][BPh4] were determined by X-ray crystallography. Reaction of vanadocene dichlorides (Cp2VCl2 and (C5H4Me)2VCl2) with amino acids containing secondary amino groups gives three types of complexes: a) compounds with N,O-bonded amino acid, b) O-bonded amino acids and c) O,O-bonded amino acid. The complexes with N,O-bonded amino acid and O-bonded amino acids were observed in the case of L-proline and N-methylglycine (NMG). Reactions with N-phenylglycine (NPG) give O,O-chelates as the sole products. All three types of the complexes were characterized by spectroscopic methods. Structures of [(C5H4Me)2V(O-Pro)][BPh4], [Cp2V(O-Pro)2][PF6]2, [Cp2V(N,O-NMG)][BPh4], [(C5H4Me)2V(N,O-NMG)][BPh4], [Cp2V(O-NMG)2][Cl]2, [(C5H4Me)2V(O-NMG)2][Cl]2 and [(C5H4Me)2V(O,O-NPG)][BPh4] were determined by X-ray crystallography. (en)
Title	Vanadocene complexes of amino acids containing secondary amino group: The first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety. Vanadocene complexes of amino acids containing secondary amino group: The first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety. (en)
skos:prefLabel	Vanadocene complexes of amino acids containing secondary amino group: The first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety. Vanadocene complexes of amino acids containing secondary amino group: The first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety. (en)
skos:notation	RIV/00216275:25310/10:39882940!RIV11-GA0-25310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/09/0460), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	9
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Vinklárek, Jaromír Růžička, Aleš Honzíček, Jan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	295244
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/10:39882940
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	EPR; X-ray; amino acids; vanadocene complexes (en)
http://linked.open.../riv/klicoveSlovo	EPR X-ray amino acids vanadocene complexes
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[6CB3FA93E2FC]
http://linked.open...i/riv/nazevZdroje	Journal of Inorganic Biochemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Experimental and theoretical study metallocene complexes with biological activity
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	104
http://linked.open...iv/tvurceVysledku	Růžička, Aleš Vinklárek, Jaromír Honzíček, Jan Dědourková, Tereza
http://linked.open...ain/vavai/riv/wos	000280679200006
http://linked.open...n/vavai/riv/zamer	Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	0162-0134
number of pages	8 (xsd:int)
http://localhost/t...ganizacniJednotka	25310
is http://linked.open...avai/riv/vysledek of	Vanadocene complexes of amino acids containing secondary amino group: The first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety. Vanadocene complexes of amino acids containing secondary amino group: The first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety. Vanadocene complexes of amino acids containing secondary amino group: The first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety.

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