About: C,N-chelated dicyclopentadienylzirconium complexes and their possible use as hydrogenation catalysts     Goto   Sponge   NotDistinct   Permalink

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Description
  • In situ generated Cp2Zr(n-Bu)Cl (6) reacts with {2-[(CH3)2NCH2]C6H4}2Pb to form exclusively {2-[(CH3)2NCH2]C6H4}Cp2ZrCl (7), [(CH3)2NCH2]C6H5, butene and elemental lead. The further derivatization of chloride (7) to fluoride (8), hydride (9), methyl derivative (10), and a reduction of 7 are also described. The crystal structures of 7-10 were determined. The catalytic activity of 9 and 10 in hydrogenation of styrene was also preliminarily tested
  • In situ generated Cp2Zr(n-Bu)Cl (6) reacts with {2-[(CH3)2NCH2]C6H4}2Pb to form exclusively {2-[(CH3)2NCH2]C6H4}Cp2ZrCl (7), [(CH3)2NCH2]C6H5, butene and elemental lead. The further derivatization of chloride (7) to fluoride (8), hydride (9), methyl derivative (10), and a reduction of 7 are also described. The crystal structures of 7-10 were determined. The catalytic activity of 9 and 10 in hydrogenation of styrene was also preliminarily tested (en)
Title
  • C,N-chelated dicyclopentadienylzirconium complexes and their possible use as hydrogenation catalysts
  • C,N-chelated dicyclopentadienylzirconium complexes and their possible use as hydrogenation catalysts (en)
skos:prefLabel
  • C,N-chelated dicyclopentadienylzirconium complexes and their possible use as hydrogenation catalysts
  • C,N-chelated dicyclopentadienylzirconium complexes and their possible use as hydrogenation catalysts (en)
skos:notation
  • RIV/00216275:25310/10:39882371!RIV11-GA0-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GAP106/10/0924), P(KJB401550802)
http://linked.open...iv/cisloPeriodika
  • 12
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
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http://linked.open...dnocenehoVysledku
  • 251021
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/10:39882371
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • dicyclopentadienylzirconium complexes, hydrogenation catalysts (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [EEDE515EC060]
http://linked.open...i/riv/nazevZdroje
  • Inorganic Chemistry Communications
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 13
http://linked.open...iv/tvurceVysledku
  • Padělková, Zdeňka
  • Růžička, Aleš
  • Bareš, Josef
  • Meunier, Philippe
  • Pirio, Nadine
issn
  • 1387-7003
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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